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author:

Wu, Shao-Hua (Wu, Shao-Hua.) [1] (Scholars:吴韶华) | Sun, Jian Jun (Sun, Jian Jun.) [2] (Scholars:孙建军) | Lin, Zhi-Bin (Lin, Zhi-Bin.) [3] | Wu, Ai-Hong (Wu, Ai-Hong.) [4] | Zeng, Yong-Ming (Zeng, Yong-Ming.) [5] | Guo, Liang (Guo, Liang.) [6] | Zhang, De-Feng (Zhang, De-Feng.) [7] | Dai, Hui-Ming (Dai, Hui-Ming.) [8] | Chen, Guo-Nan (Chen, Guo-Nan.) [9] (Scholars:陈国南)

Indexed by:

Scopus SCIE

Abstract:

Electrically heated graphite cylindrical electrodes (HGCEs) made from ground pencil leads have been used to perform adsorptive stripping square wave voltammetry (SWV) measurements of trace riboflavin (RF). The SWV stripping peak current was significantly enhanced with increasing the electrode temperature only during preconcentration step. This enhancement was due to the forced thermal convection induced by heating the electrode rather than the bulk solution. It is the thermal convection that has the ability to improve mass transfer and facilitate adsorption thus enhance stripping responses. It was found that the detection limit of 5 x 10(-9) M (S/N= 3) could be obtained at an electrode temperature of 72 degrees C during 5 min accumulation, more than one magnitude lower than that at 22 degrees C (room temperature), the sensitivity could be enhanced ca. eight or four folds for two different RF concentration ranges. So it is possible to develop a new highly sensitive method to determine riboflavin at HGCEs. Such HGCEs were also successfully used to determine RF in multivitamin tablets.

Keyword:

adsorptive stripping analysis heated graphite cylindrical electrodes riboflavin square-wave voltammetry

Community:

  • [ 1 ] Fuzhou Univ, Coll Chem & Chem Engn, Key Lab Analysis & Detect Technol Food Safety, Minist Educ, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 孙建军

    [Sun, Jian Jun]Fuzhou Univ, Coll Chem & Chem Engn, Key Lab Analysis & Detect Technol Food Safety, Minist Educ, Fuzhou 350002, Peoples R China

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Source :

ELECTROANALYSIS

ISSN: 1040-0397

Year: 2007

Issue: 21

Volume: 19

Page: 2251-2257

2 . 9 4 9

JCR@2007

2 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 35

SCOPUS Cited Count: 36

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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