• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Wu Shao-Hua (Wu Shao-Hua.) [1] (Scholars:吴韶华) | Nie Fa-Hui (Nie Fa-Hui.) [2] | Lin Zhi-Bin (Lin Zhi-Bin.) [3] | Dai Hui-Ming (Dai Hui-Ming.) [4] | Zhang De-Feng (Zhang De-Feng.) [5]

Indexed by:

Scopus SCIE PKU CSCD

Abstract:

Electrically heated graphite cylindrical electrodes (HGCEs) have been used to perform electrochemical behavior studies and adsorptive stripping square wave voltammetric (SWV) measurements of flavin adenine dinucleotide (FAD). It was found that when the electrode with adsorbed FAD was heated during cyclic voltammetric cycling, the redox peak potential shifted negatively, peak current diminished and the peak shape became poorer. While the SWV stripping peak current was significantly enhanced with increasing the electrode temperature only during preconcentration step. This enhancement was due to the forced thermal convection induced by heating the electrode rather than the bulk solution. It is the thermal convection that has the ability to improve mass thransfer and facilitate adsorption thus enhance stripping responses. It was found that the detection limit of 1 x 10(-8) mol/L (S/N = 3) could be obtained at an electrode temperature of 72 degrees C during 5 min accumulation, about one magnitude less than that at room temperature 27 degrees C. The sensitivity was also improved significantly.

Keyword:

adsorptive stripping analysis Flavin adenine dinucleotide heated graphite cylindrical electrodes square wave voltammetric

Community:

  • [ 1 ] [Wu Shao-Hua]Fuzhou Univ, Coll Chem & Chem Engn, Minist Educ, Key Lab Anal & Detect Technol Food Safety, Fuzhou 350002, Peoples R China
  • [ 2 ] [Nie Fa-Hui]Fuzhou Univ, Coll Chem & Chem Engn, Minist Educ, Key Lab Anal & Detect Technol Food Safety, Fuzhou 350002, Peoples R China
  • [ 3 ] [Lin Zhi-Bin]Fuzhou Univ, Coll Chem & Chem Engn, Minist Educ, Key Lab Anal & Detect Technol Food Safety, Fuzhou 350002, Peoples R China
  • [ 4 ] [Dai Hui-Ming]Fuzhou Univ, Coll Chem & Chem Engn, Minist Educ, Key Lab Anal & Detect Technol Food Safety, Fuzhou 350002, Peoples R China
  • [ 5 ] [Zhang De-Feng]Fuzhou Univ, Coll Chem & Chem Engn, Minist Educ, Key Lab Anal & Detect Technol Food Safety, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 吴韶华

    [Wu Shao-Hua]Fuzhou Univ, Coll Chem & Chem Engn, Minist Educ, Key Lab Anal & Detect Technol Food Safety, Fuzhou 350002, Peoples R China

Show more details

Related Keywords:

Source :

CHINESE JOURNAL OF ANALYTICAL CHEMISTRY

ISSN: 0253-3820

CN: 22-1125/O6

Year: 2008

Issue: 9

Volume: 36

Page: 1228-1232

0 . 6 3 3

JCR@2008

1 . 2 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

Online/Total:242/9977662
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1