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Electrically heated graphite cylindrical electrodes (HGCEs) have been used to perform electrochemical behavior studies and adsorptive stripping square wave voltammetric (SWV) measurements of flavin adenine dinucleotide (FAD). It was found that when the electrode with adsorbed FAD was heated during cyclic voltammetric cycling, the redox peak potential shifted negatively, peak current diminished and the peak shape became poorer. While the SWV stripping peak current was significantly enhanced with increasing the electrode temperature only during preconcentration step. This enhancement was due to the forced thermal convection induced by heating the electrode rather than the bulk solution. It is the thermal convection that has the ability to improve mass thransfer and facilitate adsorption thus enhance stripping responses. It was found that the detection limit of 1 x 10(-8) mol/L (S/N = 3) could be obtained at an electrode temperature of 72 degrees C during 5 min accumulation, about one magnitude less than that at room temperature 27 degrees C. The sensitivity was also improved significantly.
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CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
ISSN: 0253-3820
CN: 22-1125/O6
Year: 2008
Issue: 9
Volume: 36
Page: 1228-1232
0 . 6 3 3
JCR@2008
1 . 2 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:4
Cited Count:
WoS CC Cited Count: 1
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
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