A　novel　1-D　organic-inorganic　silver(I)-iodide　coordination　architecture　[(C10H16N)(3)(Ag6I9)]　(n)　(1)　(C10H16N+=N-butyl-2-methyl-pyridinium)　templated　by　appropriate　cation　has　been　constructed　and　structurally　and　optically　characterized.　The　inorganic　moiety　of　1　presents　one-dimensional　hackle　chain　arrangement　that　results　from　the　edges-sharing　of　AgI4　tetrahedrons.　Static　attracting　interactions　between　organic　counter　cations　and　inorganic　chains　are　presented　and　contribute　to　the　crystal　packing.　The　optical　limiting　experiment　shows　that　the　present　polymer　exhibits　a　large　optical　limiting　capacity.