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学者姓名:胡晓琳

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红色荧光粉CaAlSiN_3∶Eu~(2+)的结构精修和性能 PKU
期刊论文 | 2024 , 52 (02) , 207-212 | 福州大学学报(自然科学版)
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Abstract :

运用高温固相法合成系列掺铕(Eu)的氮化物荧光粉Ca_(1-)_xAlSiN_3∶xEu~(2+),对所得到的最佳样品Ca_(0.99)AlSiN_3∶0.01Eu~(2+)进行系列表征和结构精修.结果表明,样品Ca_(0.99)AlSiN_3∶0.01Eu~(2+)的晶粒尺寸为10μm左右,各元素分布均匀,其精修图与实测XRD谱图基本吻合,属于正交晶系结构.该样品的色坐标为(0.645 1, 0.354 5),落在红光区域,色纯度高达100%,相关色温为2 449 K,属于低色温.该荧光粉在298~473 K范围内表现出良好的热稳定性,活化能为0.26 eV,具有广阔的市场前景.

Keyword :

Rietveld精修 Rietveld精修 发光性能 发光性能 热稳定性 热稳定性 红色荧光粉 红色荧光粉 铕掺杂 铕掺杂

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GB/T 7714 林莹 , 刘梦丽 , 冯嘉雯 et al. 红色荧光粉CaAlSiN_3∶Eu~(2+)的结构精修和性能 [J]. | 福州大学学报(自然科学版) , 2024 , 52 (02) : 207-212 .
MLA 林莹 et al. "红色荧光粉CaAlSiN_3∶Eu~(2+)的结构精修和性能" . | 福州大学学报(自然科学版) 52 . 02 (2024) : 207-212 .
APA 林莹 , 刘梦丽 , 冯嘉雯 , 郑文旭 , 胡晓琳 , 庄乃锋 . 红色荧光粉CaAlSiN_3∶Eu~(2+)的结构精修和性能 . | 福州大学学报(自然科学版) , 2024 , 52 (02) , 207-212 .
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红色荧光粉CaAlSiN3∶Eu2+的结构精修和性能 PKU
期刊论文 | 2024 , 52 (2) , 207-212 | 福州大学学报(自然科学版)
立方相BiFeO_3磁光晶体的熔盐法制备与性能分析 CSCD PKU
期刊论文 | 2024 , 44 (14) , 189-198 | 光学学报
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Abstract :

采用熔盐法,以Bi_2O_3为自助溶剂,成功制备了Sr/Ti∶BiFeO_3系列晶体。X射线衍射谱和Rietveld精修结果显示,Sr~(2+)、Ti~(4+)离子掺杂使BiFeO_3的结构从三方相转变为无双折射的立方相。这一结构转变也通过扫描电子显微镜的观察得到了证实。Sr/Ti∶BiFeO_3的X射线光电子能谱表明,随着Sr~(2+)、Ti~(4+)的引入,BiFeO_3的Fe元素价态发生改变。高价Fe离子的生成使BiFeO_3产生晶格畸变,并对其周期性螺旋自旋磁结构产生抑制作用,从而使BiFeO_3的宏观磁性得到提高,但矫顽力没有发生明显变化。晶体磁滞回线和磁圆二色效应光谱显示,Bi_(0.7)Sr_(0.3)Fe_(0.7)Ti_(0.3)O_3的饱和磁化强度较BiFeO_3提高了3倍,其磁光效应达到商用Y_3Fe_5O_(12)的4.5倍。

Keyword :

BiFeO_3 BiFeO_3 材料 材料 熔盐法 熔盐法 磁光晶体 磁光晶体 磁圆二色性 磁圆二色性 磁性 磁性

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GB/T 7714 林楠茜 , 杨新攀 , 许晨浚 et al. 立方相BiFeO_3磁光晶体的熔盐法制备与性能分析 [J]. | 光学学报 , 2024 , 44 (14) : 189-198 .
MLA 林楠茜 et al. "立方相BiFeO_3磁光晶体的熔盐法制备与性能分析" . | 光学学报 44 . 14 (2024) : 189-198 .
APA 林楠茜 , 杨新攀 , 许晨浚 , 吴华钦 , 张宏 , 庄乃锋 et al. 立方相BiFeO_3磁光晶体的熔盐法制备与性能分析 . | 光学学报 , 2024 , 44 (14) , 189-198 .
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Structure and Magnetic and Magneto-Optical Properties of a New Cubic Ce3Sc2Ga3O12 Garnet Crystal with Heavy Ce3+ Concentration SCIE
期刊论文 | 2024 , 24 (10) , 4086-4093 | CRYSTAL GROWTH & DESIGN
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Based on the thermal stability analysis by density functional theory and the crystal phase optimization by tolerance factor, the crystal structure was designed. So, a new cubic Ce3Sc2Ga3O12 (CSGG) garnet material with a high Ce3+ concentration was synthesized. The centimeter-scale CSGG crystal was grown by the Czochralski method. CSGG exhibits fine magneto-optical properties, which are attributed to the stable valence and high concentration of rare-earth Ce3+ ions. Compared with commercial Tb3Ga5O12 (TGG), CSGG is also paramagnetic, but its magneto-optical properties are better. The Verdet constants of CSGG in 532, 635, 1064, and 1550 nm are -380.0, -258.8, -47.5, and -22.4 rad/Tm, respectively, which are from 1.2 to 2.0 times that of TGG. Moreover, the CSGG crystal has high transmittance in 1500-2300 nm to make up for the poor transmittance of TGG crystal in this band. Also, considering its low raw material cost, the CSGG crystal presents promising application potential. It could be qualified as an essential material for magneto-optical isolators, circulators, and switches within the visible to mid-infrared band.

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GB/T 7714 Liu, Mengli , Wang, Ningjing , Zhang, Liangchen et al. Structure and Magnetic and Magneto-Optical Properties of a New Cubic Ce3Sc2Ga3O12 Garnet Crystal with Heavy Ce3+ Concentration [J]. | CRYSTAL GROWTH & DESIGN , 2024 , 24 (10) : 4086-4093 .
MLA Liu, Mengli et al. "Structure and Magnetic and Magneto-Optical Properties of a New Cubic Ce3Sc2Ga3O12 Garnet Crystal with Heavy Ce3+ Concentration" . | CRYSTAL GROWTH & DESIGN 24 . 10 (2024) : 4086-4093 .
APA Liu, Mengli , Wang, Ningjing , Zhang, Liangchen , Liu, Haipeng , Feng, Jiawen , Gao, Teng et al. Structure and Magnetic and Magneto-Optical Properties of a New Cubic Ce3Sc2Ga3O12 Garnet Crystal with Heavy Ce3+ Concentration . | CRYSTAL GROWTH & DESIGN , 2024 , 24 (10) , 4086-4093 .
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Structure and Magnetic and Magneto-Optical Properties of a New Cubic Ce3Sc2Ga3O12 Garnet Crystal with Heavy Ce3+ Concentration EI
期刊论文 | 2024 , 24 (10) , 4086-4093 | Crystal Growth and Design
Structure and Magnetic and Magneto-Optical Properties of a New Cubic Ce3Sc2Ga3O12 Garnet Crystal with Heavy Ce3+ Concentration Scopus
期刊论文 | 2024 , 24 (10) , 4086-4093 | Crystal Growth and Design
Preparation and Properties of Cubic Phase BiFeO3 Magneto-Optical Crystals by Molten Salt Method; [立方相 BiFeO3磁光晶体的熔盐法制备与性能] Scopus
期刊论文 | 2024 , 44 (14) | Acta Optica Sinica
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Objective Magneto-optical crystals are pivotal components that determine the performance of magneto-optical devices. Through the hybridization between the excited Bi3+ 6p orbital and Fe3+ 3d orbital, the modification of superexchange induces a strong mixing between crystal field states of varying energies, greatly enhancing the magneto-optic effect in ferrite. Doping Bi3+ ions emerges as a key approach to enhancing the magneto-optical properties of commercial Y3Fe5O12 (YIG) crystals. However, despite being the only known room temperature single-phase multiferroic material, there is scarce literature reporting on the magneto-optical properties and its applications in magneto-optical devices of the perovskite BiFeO3 with a high concentration of Bi3+ . This can be attributed to its unique spiral G-type antiferromagnetic structure, which exhibits weak macroscopic magnetism. Additionally, due to its trigonal crystal system and birefringence effect, BiFeO3 demonstrates a considerably feeble magneto-optical effects. In the present study, stable pure phase cubic BiFeO3 single crystals are grown by doping Sr2+ and Ti4+ ions. This eliminates the birefringence effect of the trigonal BiFeO3 and induces strong magnetic and magneto-optical effects, providing a useful reference for exploring high-quality, large-size new magneto-optical crystals suitable for high-performance magneto-optical devices. Methods Bi2O3 is chosen as the self-flux solvent, and a series of crystals including Bi1-xSrxFeO3 and Bi1-xSrxFe1-xTixO3 (x=0‒0.5) are grown by using the molten salt method. The crystal structure and lattice parameters of Sr∶BiFeO3 and Sr/Ti∶BiFeO3 are determined by XRD spectra analysis and Rietveld refinement. The structure and morphology changes of BiFeO3 crystals are observed by scanning electron microscopy (SEM). Elemental valence states in the crystals are analyzed using X-ray photoelectron spectroscopy (XPS), while magnetic properties and magneto-optical performance are characterized by a vibrating sample magnetometer and magneto-circular dichroism spectroscopy respectively. Results and Discussions The Rietveld refinement results show that Bi0.7Sr0.3FeO3 and Bi0.7Sr0.3Fe0.7Ti0.3O3 crystals belong to the Pm-3m space group of the cubic crystal system. The cell parameters of Bi0.7Sr0.3FeO3 and Bi0.7Sr0.3Fe0.7Ti0.3O3 crystals are 3.9517 Å and 3.9447 Å, respectively. The SEM images also prove that BiFeO3 changes from a triangular columnar crystal to regular cubic crystals. When the cooling rate of crystal growth is controlled within the range of 1‒10 ℃/h, the size of cubic crystal grains are 20‒50 μm. Sub-millimeter size crystal grains are obtained when the cooling rate of crystal growth is 0.5 ℃/h. However, as the grain size increases, the distance between the stress field of the dislocation packing group and the dislocation source in the crystal also increases, resulting in a stronger stress field and subsequent grain deformation. XPS spectra show that doping of heterovalent elements leads to the production of Fe2+ and high-valence iron. The saturated hysteresis loop and MCD spectra indicate that the magnetic and magneto-optical properties of BiFeO3 crystal can be significantly enhanced by doping of Sr2+ and Ti4+ ions, but the coercivity has not significantly changed. The saturation magnetization of Bi0.7Sr0.3Fe0.7Ti0.3O3 is observed to be 0.31 (A·m2)/kg, which is approximately four times that of BiFeO3, while exhibiting a significant MCD ellipticity value (ψF) of 179 (°)/cm, in contrast to the negligible MCD signal produced by BiFeO3 (Fig. 7 and Fig. 8). This can be attributed to the introduction of Sr2+ and Ti4+ ions, leading to the elimination of the birefringence effect, as well as the suppression of the periodic spiral spin magnetic structure and providing additional electronic transition pathways. Consequently, this enhances both the magnetic and magneto-optical properties of BiFeO3 crystals. Conclusions A series of non-birefringent cubic Bi1-xSrxFeO3 (x=0.3, 0.4, 0.5) and Bi1-xSrxFe1-xTixO3 (x=0.2, 0.3, 0.4, 0.5) crystals are grown by using the molten salt method. The introduction of Sr2+ and Ti4+ ions causes lattice distortion of BiFeO3 and inhibits its periodic helical spin magnetic structure. Especially, when Ti4+ ions are introduced to replace part of Fe3+, the helical G-type antiferromagnetic structure of BiFeO3 will be broken, thereby releasing part of the spin magnetic moment of Fe ions. This results in the magnetism and magneto-optical effects of Sr∶BiFeO3 and Sr/Ti ∶BiFeO3 are significantly stronger than that of BiFeO3. The saturation magnetization of Bi0.7Sr0.3Fe0.7Ti0.3O3 is approximately 4 times that of BiFeO3. Its MCD ψF value is observed to be 179 (°)/cm, which is about 4.5 times that of YIG, a popular commercial magneto-optical material tested under the same conditions. With high saturation magnetization, low coercivity and strong magneto-optical effect, Sr/Ti∶BiFeO3 crystals are expected to be used as core magneto-optical materials in magneto-optical modulation, magneto-optical sensing, magneto-optical imaging and other devices, and are hopefully applied in optical communication, laser display, biomedicine, etc. © 2024 Chinese Optical Society. All rights reserved.

Keyword :

BiFeO3 BiFeO3 magnetic circular dichroism magnetic circular dichroism magnetism magnetism magneto-optical crystal magneto-optical crystal materials materials molten salt method molten salt method

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GB/T 7714 Lin, N. , Yang, X. , Xu, C. et al. Preparation and Properties of Cubic Phase BiFeO3 Magneto-Optical Crystals by Molten Salt Method; [立方相 BiFeO3磁光晶体的熔盐法制备与性能] [J]. | Acta Optica Sinica , 2024 , 44 (14) .
MLA Lin, N. et al. "Preparation and Properties of Cubic Phase BiFeO3 Magneto-Optical Crystals by Molten Salt Method; [立方相 BiFeO3磁光晶体的熔盐法制备与性能]" . | Acta Optica Sinica 44 . 14 (2024) .
APA Lin, N. , Yang, X. , Xu, C. , Wu, H. , Zhang, H. , Zhuang, N. et al. Preparation and Properties of Cubic Phase BiFeO3 Magneto-Optical Crystals by Molten Salt Method; [立方相 BiFeO3磁光晶体的熔盐法制备与性能] . | Acta Optica Sinica , 2024 , 44 (14) .
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Preparation by Molten Salt Method and Properties Analysis of Cubic Phase BiFeO3 Magneto-Optical Crystals
期刊论文 | 2024 , 44 (14) | ACTA OPTICA SINICA
Preparation and Properties of Cubic Phase BiFeO3 Magneto-Optical Crystals by Molten Salt Method EI
期刊论文 | 2024 , 44 (14) | Acta Optica Sinica
Growth and Piezoelectric Properties of Centimeter-Size BiFeO3 Single Crystals Codoped with Sr and Ti Ions SCIE
期刊论文 | 2024 , 24 (21) , 8914-8920 | CRYSTAL GROWTH & DESIGN
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A BiFeO3 crystal has both antiferromagnetism and piezoelectricity at room temperature. Unfortunately, it is difficult to grow a larger-size and high-quality BiFeO3 single crystal. By a top-seeded solution growth method using Bi2O3 as a solvent, centimeter-size Bi1-x Sr x Fe1-y Ti y O3 crystals were successfully grown in this paper. Moreover, the lattice symmetry of the Bi1-x Sr x Fe1-y Ti y O3 crystals changes from rhombohedra to cube with the increase in Sr2+ and Ti4+ doping concentration. The magnetization of a Bi0.6Sr0.4Fe0.6Ti0.4O3 crystal reaches 0.25 emu/g at room temperature, which is about 3.1 times as large as that of a BiFeO3 single crystal, in an applied magnetic field of 10,000 Oe. The piezoelectric effect is observed on all Bi0.8Sr0.2Fe0.8Ti0.2O3-2 wafers; especially, strong response was observed on the < 111 >-oriented wafer. By optimizing the type and the concentration of doped ions, it is expected to obtain large-size doped BiFeO3 single crystals with better magnetic and piezoelectric properties.

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GB/T 7714 Cao, Qinyu , Liang, Jinlun , Zhang, Liangchen et al. Growth and Piezoelectric Properties of Centimeter-Size BiFeO3 Single Crystals Codoped with Sr and Ti Ions [J]. | CRYSTAL GROWTH & DESIGN , 2024 , 24 (21) : 8914-8920 .
MLA Cao, Qinyu et al. "Growth and Piezoelectric Properties of Centimeter-Size BiFeO3 Single Crystals Codoped with Sr and Ti Ions" . | CRYSTAL GROWTH & DESIGN 24 . 21 (2024) : 8914-8920 .
APA Cao, Qinyu , Liang, Jinlun , Zhang, Liangchen , Wu, Junying , Gao, Teng , Hu, Xiaolin et al. Growth and Piezoelectric Properties of Centimeter-Size BiFeO3 Single Crystals Codoped with Sr and Ti Ions . | CRYSTAL GROWTH & DESIGN , 2024 , 24 (21) , 8914-8920 .
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Growth and Piezoelectric Properties of Centimeter-Size BiFeO3 Single Crystals Codoped with Sr and Ti Ions EI
期刊论文 | 2024 , 24 (21) , 8914-8920 | Crystal Growth and Design
Growth and Piezoelectric Properties of Centimeter-Size BiFeO3 Single Crystals Codoped with Sr and Ti Ions Scopus
期刊论文 | 2024 , 24 (21) , 8914-8920 | Crystal Growth and Design
A new Ni/Bi Co-doping rare earth iron garnet crystal with high transmittance, low temperature and wavelength coefficients SCIE
期刊论文 | 2024 , 978 | JOURNAL OF ALLOYS AND COMPOUNDS
WoS CC Cited Count: 1
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Bi-doped rare earth iron garnet (Bi:RIG) crystal is an ideal magneto-optical material for optical isolators in the near-infrared band, which has been widely used in optical communication applications. In this paper, centimetersized and good-quality Ni2+-doped Bi:RIG crystals were successfully grown by top-seeded solution growth (TSSG). The transmittance reaches 72.6% at 1550 nm, which is higher than commercial Bi:TbIG crystal and close to the theoretical values of RIG crystals. Doping Ni can not only greatly improve the transmittance, magnetic, and magneto-optical properties, but also decrease the Faraday rotation temperature (FTC) and wavelength coefficients (FWC) of the Bi:RIG crystal. The FTC and FWC of (Bi0.37Ho1.18Eu0.83Gd0.62)(Fe4.20Ni0.25Ga0.55)O-12 crystal reduced to - 6.3 x 10(-4) K-1 and 8.0 x 10(-4) nm(-1), which are about 30% and 80% of commercial Bi:TbIG crystal, respectively. (Bi0.37Ho1.18Eu0.83Gd0.62)(Fe4.20Ni0.25Ga0.55)O-12 exhibits potential for utilization in new high -performance, wideband magneto-optical isolators, and is expected to find application in the field of wavelength division multiplexing fiber communication.

Keyword :

Crystal growth Crystal growth Magneto-optical material Magneto-optical material Ni/Bi co-doping Ni/Bi co-doping Rare earth iron garnet Rare earth iron garnet Top seeded solution growth Top seeded solution growth

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GB/T 7714 Yang, Yanduan , Fan, Xiaoyu , Liu, Haipeng et al. A new Ni/Bi Co-doping rare earth iron garnet crystal with high transmittance, low temperature and wavelength coefficients [J]. | JOURNAL OF ALLOYS AND COMPOUNDS , 2024 , 978 .
MLA Yang, Yanduan et al. "A new Ni/Bi Co-doping rare earth iron garnet crystal with high transmittance, low temperature and wavelength coefficients" . | JOURNAL OF ALLOYS AND COMPOUNDS 978 (2024) .
APA Yang, Yanduan , Fan, Xiaoyu , Liu, Haipeng , Wu, Junying , Yang, Yang , Chen, Xin et al. A new Ni/Bi Co-doping rare earth iron garnet crystal with high transmittance, low temperature and wavelength coefficients . | JOURNAL OF ALLOYS AND COMPOUNDS , 2024 , 978 .
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A new Ni/Bi Co-doping rare earth iron garnet crystal with high transmittance, low temperature and wavelength coefficients Scopus
期刊论文 | 2024 , 978 | Journal of Alloys and Compounds
A new Ni/Bi Co-doping rare earth iron garnet crystal with high transmittance, low temperature and wavelength coefficients EI
期刊论文 | 2024 , 978 | Journal of Alloys and Compounds
Greatly Enhanced Magnetic and Magneto-Optical Properties of Bismuth Iron Oxide Sillenite Crystal with Cobalt-Iron Codoping SCIE
期刊论文 | 2024 , 12 (10) | ADVANCED OPTICAL MATERIALS
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The chiral sillenite Bi25FeO40 exhibits versatile properties including electro-optics, magneto-optics, optical rotation, and photorefraction, showing great potential in multi-functional magneto-optical devices. However, the weak magnetism of this crystal leads to a poor magneto-optical property, which is extremely hindering its practical applications. Combining with the sillenite structure, the formation energy and the magnetic-optical effect are calculated based on density functional theory. The codoping of strongly magnetic Co and Fe ions is predicted to enable high doping concentrations. The hybridization between Bi 6p orbitals and Fe/Co 3d orbitals significantly enhances the optical transition and thus greatly improves the magneto-optical properties. The millimeter-sized Bi26-x-yCoxFeyO40 crystals are successfully prepared by hydrothermal methods. The characterizations on structure, TG-DSC, magnetism, and magneto-optical effect confirm the theoretical predictions that the Co-Fe codoped crystals maintain the chiral bismuth ferrite structure with multifunctional properties and high thermal stability. The Co-Fe codoping significantly enhances the magnetism and magneto-optical properties of Bi25FeO40 crystal. The magnetization of Bi19.0Co3.5Fe3.5O40 increases by 27 times and the magneto-optical effect of Bi19.8Co3.0Fe3.2O40 at 720, 777, 1288, 1388, and 1790 nm are greater than Bi:YIG and undoped Bi25FeO40. Bi26-x-yCoxFeyO40 crystals with enhanced magneto-optical properties by Co-Fe codoping are promising for novel multifunctional magneto-optical devices. DFT calculation is a feasible way for predicting the magneto-optical Faraday rotation angle of Bi25FeO40 sillenite crystal. A series of cubic Bi26-x-yCoxFeyO40 crystals are prepared by hydrothermal method. Bi19.8Co3.0Fe3.2O40 crystal has a stronger magneto-optical effect than the commercial Bi:YIG crystal in 1500-1800 nm. It opens up new possibility for the creation of novel multiple functions magneto-optical devices. image

Keyword :

density functional theory calculation density functional theory calculation magnetism magnetism magneto-optical effect magneto-optical effect rietveld refinement rietveld refinement sillenite crystals sillenite crystals

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GB/T 7714 Liu, Meng-Li , Wang, Cheng , Wu, Xuan et al. Greatly Enhanced Magnetic and Magneto-Optical Properties of Bismuth Iron Oxide Sillenite Crystal with Cobalt-Iron Codoping [J]. | ADVANCED OPTICAL MATERIALS , 2024 , 12 (10) .
MLA Liu, Meng-Li et al. "Greatly Enhanced Magnetic and Magneto-Optical Properties of Bismuth Iron Oxide Sillenite Crystal with Cobalt-Iron Codoping" . | ADVANCED OPTICAL MATERIALS 12 . 10 (2024) .
APA Liu, Meng-Li , Wang, Cheng , Wu, Xuan , Shen, Jin-Ru , Gao, Teng , Chen, Xin et al. Greatly Enhanced Magnetic and Magneto-Optical Properties of Bismuth Iron Oxide Sillenite Crystal with Cobalt-Iron Codoping . | ADVANCED OPTICAL MATERIALS , 2024 , 12 (10) .
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Greatly Enhanced Magnetic and Magneto‐Optical Properties of Bismuth Iron Oxide Sillenite Crystal with Cobalt–Iron Codoping
期刊论文 | 2024 , 12 (10) , n/a-n/a | Advanced Optical Materials
Greatly Enhanced Magnetic and Magneto-Optical Properties of Bismuth Iron Oxide Sillenite Crystal with Cobalt–Iron Codoping Scopus
期刊论文 | 2024 , 12 (10) | Advanced Optical Materials
Greatly Enhanced Magnetic and Magneto-Optical Properties of Bismuth Iron Oxide Sillenite Crystal with Cobalt–Iron Codoping EI
期刊论文 | 2024 , 12 (10) | Advanced Optical Materials
Interface polarity brings a way to modulate magneto-optical effect of cubic Ni2+/Fe3+co-doped Bi25FeO40 film: Implications in piezoelectricity SCIE
期刊论文 | 2024 , 659 | APPLIED SURFACE SCIENCE
WoS CC Cited Count: 3
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Cubic Sillenite Bi25FeO40 (BFO) could become a new magneto-optical material due to its high concentration of Bi3+ and no birefringence. But its weak magnetism causes the magneto-optical properties to be far from the requirements of practical applications. Doping magnetic Fe3+ and Ni2+ ions to improve the magnetism and magneto-optical properties of BFO (Bi19Ni2.8Fe4.2O40) film on fluorine-doped tin oxide (BNFO/FTO) is discussed in this paper. Another focus of this paper is to discuss the magneto-optical properties modulated by the electric field. The cubic BNFO film has weak piezoelectric effects, which makes it difficult to modulate its magnetooptical effect by electric field. A polarity symmetry induced by the Schottky junction between Au metal layer and BNFO semiconductor layer (Au/BNFO) compensates for cubic symmetry, and the piezoelectric effect can be improved. By applying an electric field, its magnetic circular dichroism (MCD) ellipticity |Psi F| gradually decreases as a direct current voltage from 0 V to 10 V in a magnetic field of 2500 Oe, demonstrating the feasibility of this strategy. These results indicate a new way for highly symmetric magneto-optical materials to modulate magneto-optical effects in electric fields.

Keyword :

Au/BNFO/FTO film Au/BNFO/FTO film Magneto -electric coupling Magneto -electric coupling Magneto -optical effect Magneto -optical effect Piezoelectric effect Piezoelectric effect

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GB/T 7714 Gao, Teng , Wu, Junying , Liang, Jinlun et al. Interface polarity brings a way to modulate magneto-optical effect of cubic Ni2+/Fe3+co-doped Bi25FeO40 film: Implications in piezoelectricity [J]. | APPLIED SURFACE SCIENCE , 2024 , 659 .
MLA Gao, Teng et al. "Interface polarity brings a way to modulate magneto-optical effect of cubic Ni2+/Fe3+co-doped Bi25FeO40 film: Implications in piezoelectricity" . | APPLIED SURFACE SCIENCE 659 (2024) .
APA Gao, Teng , Wu, Junying , Liang, Jinlun , Wang, Cheng , Liu, Mengli , Yang, Yanduan et al. Interface polarity brings a way to modulate magneto-optical effect of cubic Ni2+/Fe3+co-doped Bi25FeO40 film: Implications in piezoelectricity . | APPLIED SURFACE SCIENCE , 2024 , 659 .
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Interface polarity brings a way to modulate magneto-optical effect of cubic Ni2+/Fe3+ co-doped Bi25FeO40 film: Implications in piezoelectricity Scopus
期刊论文 | 2024 , 659 | Applied Surface Science
Interface polarity brings a way to modulate magneto-optical effect of cubic Ni2+/Fe3+ co-doped Bi25FeO40 film: Implications in piezoelectricity EI
期刊论文 | 2024 , 659 | Applied Surface Science
Piezoelectric and magneto-optical effect of lanthanum-doped bismuth ferrite films on silicon substrate SCIE
期刊论文 | 2023 , 967 | JOURNAL OF ALLOYS AND COMPOUNDS
WoS CC Cited Count: 2
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Abstract :

Rhombohedral La:BiFeO3 films were successfully prepared on Si substrates by using Radio frequency magnetron sputtering method. The LaNiO3 as buffer layer is beneficial for improving the quality of the film, reducing surface roughness, and getting rid of the impure phase. The Bi0.9La0.1FeO3/LaNiO3/Si film has the largest piezoelectric coefficient with d(33) reaching 4.76 pm/V, which is about 2.5 times larger than that of BiFeO3/LaNiO3/Si. The saturation magnetization and the MCD signal of BiFeO3 films are significantly enhanced by doping La3+. The MCD ellipticity of La:BiFeO3 film at 555 nm increase with the increase of La3+ concentration. Bi0.7La0.3FeO3/ LaNiO3/Si film show strong magneto-optical effect with the high MCD ellipticity of 850 deg./cm, which is more than about 1.7 times larger than that of BiFeO3 film. This film is expected to be developed into a new multifunctional material with multi-field coupling of electro-opt-magnetism.

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La:BiFeO3 La:BiFeO3 Magneto-optical effect Magneto-optical effect Piezoelectric Piezoelectric Si Substrate Si Substrate

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GB/T 7714 Cao, Qinyu , Zhao, Ying , Ye, Renjie et al. Piezoelectric and magneto-optical effect of lanthanum-doped bismuth ferrite films on silicon substrate [J]. | JOURNAL OF ALLOYS AND COMPOUNDS , 2023 , 967 .
MLA Cao, Qinyu et al. "Piezoelectric and magneto-optical effect of lanthanum-doped bismuth ferrite films on silicon substrate" . | JOURNAL OF ALLOYS AND COMPOUNDS 967 (2023) .
APA Cao, Qinyu , Zhao, Ying , Ye, Renjie , Chen, Xin , Hu, Xiaolin , Zhuang, Naifeng . Piezoelectric and magneto-optical effect of lanthanum-doped bismuth ferrite films on silicon substrate . | JOURNAL OF ALLOYS AND COMPOUNDS , 2023 , 967 .
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Piezoelectric and magneto-optical effect of lanthanum-doped bismuth ferrite films on silicon substrate Scopus
期刊论文 | 2023 , 967 | Journal of Alloys and Compounds
Piezoelectric and magneto-optical effect of lanthanum-doped bismuth ferrite films on silicon substrate EI
期刊论文 | 2023 , 967 | Journal of Alloys and Compounds
Epitaxy growth of pure phase CeFeO3 thin films with high magneto-optical performance and strong vertical magnetic anisotropy CSCD
期刊论文 | 2023 , 41 (12) , 2018-2024 | 稀土学报(英文版)
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Abstract :

The magneto-optical effects of rare earth ferrite can be greatly improved by doping Ce3+ions.CeFeO3 with high Ce3+concentration has excellent magneto-optical properties in theory.And due to its perovskite structure it is more suitable to be deposited on the substrates of optical devices compared with the commercial garnet ferrite.In this paper,the pure phase CexFe2-xO3 films were successfully obtained on the quartz glass and<100>-oriented SrTiO3 crystal substrates by radio frequency magnetron sputtering.The effects of substrate and Ce∶Fe ratio on the epitaxial orientation,magnetism and magneto-optical performance of films were systematically studied.For the Ce1.0Fe1.0O3/STO film,its MCD ellipticity(φF)intensity can reach up to 4750(°)/cm in the visible band and 14090(°)/cm in near ultraviolet band.And it also shows a strong vertical magnetic anisotropy,which makes it maintain a good thermal stability when the device size is reduced.These mean that the Ce1.0Fe1.0O3/STO film has a promising application in integrated optical communication devices.

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GB/T 7714 Nanxi Lin , Fangliang Sheng , Xin Chen et al. Epitaxy growth of pure phase CeFeO3 thin films with high magneto-optical performance and strong vertical magnetic anisotropy [J]. | 稀土学报(英文版) , 2023 , 41 (12) : 2018-2024 .
MLA Nanxi Lin et al. "Epitaxy growth of pure phase CeFeO3 thin films with high magneto-optical performance and strong vertical magnetic anisotropy" . | 稀土学报(英文版) 41 . 12 (2023) : 2018-2024 .
APA Nanxi Lin , Fangliang Sheng , Xin Chen , Xiaolin Hu , Naifeng Zhuang . Epitaxy growth of pure phase CeFeO3 thin films with high magneto-optical performance and strong vertical magnetic anisotropy . | 稀土学报(英文版) , 2023 , 41 (12) , 2018-2024 .
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