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Abstract:
The organic-inorganic hybrid [(C14H18N2)(Pb2I6)](n) ([C14H18N2](2+) = N,N'-1,4-buthylenedipyridinium (BDP)) with one-dimensional structure was self-assembling synthesized by the organic quaternary ammonium template. It crystallizes in. monoclinic, space group P2(1)/In with a = 8.2596(9), b = 15.1363(19), c = 11.1603(13) Angstrom, beta = 97.915 (5)degrees, C14H18N2Pb2I6, M-r = 1390.10, V = 1382.0(3) Angstrom(3), Z = 2, D-c = 3.341 g/cm(3), mu(MoKalpha) = 18.870 mm-(1), F(000) = 1196, the final R = 0.0420 and wR = 0.0921 for 2156 observed reflections with I > 2sigma(I). The title compound consists of cations ([C14H18N2](2+)) and anion chain ([Pb2I62-](n)) which are combined by static attractive forces in the crystal.
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CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
ISSN: 0254-5861
CN: 35-1112/TQ
Year: 2004
Issue: 9
Volume: 23
Page: 1013-1016
0 . 7 3 4
JCR@2004
5 . 9 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:3
Cited Count:
WoS CC Cited Count: 8
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
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