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author:

Bai, Shao-Jin (Bai, Shao-Jin.) [1] | Wei, Zong-Ping (Wei, Zong-Ping.) [2] | Wang, Xin (Wang, Xin.) [3] (Scholars:王欣) | Shao, Yan-Qun (Shao, Yan-Qun.) [4] (Scholars:邵艳群) | Tang, Dian (Tang, Dian.) [5] (Scholars:唐电)

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Abstract:

An IrO2-Ta2O5/Ti anode coating with molar ratio of Ir to Ta of 7:3 on titanium was prepared by a modified technology, in which a portion of nano-crystalline of IrO2 was introduced to replace some amount of H2IrCl6 in the precursor solution. The phase structure and morphology of the coating were analyzed by X-ray diffractometry (XRD) and scanning electronic microscopy (SEM), respectively. The electro-catalytic properties and electrochemical stability of the coating were also characterized by using O2 evolution polarization, cyclic voltammetry (CV) test and accelerating-life test, respectively. The results show that the crystallite phases of the nano-seeds embedded electrode coating are IrO2-based solid solution (Ir, Ta)O2 and IrO2 phase. In addition, the anodes with the nano-seeds embedded coatings exhibit better electro-catalytic activity and corrosion resistance compared with the IrO2-Ta2O5/Ti anodes prepared by the traditional method.

Keyword:

Anodes Catalyst activity Chlorine compounds Corrosion resistance Corrosion resistant coatings Cyclic voltammetry Iridium compounds Molar ratio Tantalum oxides Titanium X ray diffraction analysis

Community:

  • [ 1 ] [Bai, Shao-Jin]Institute for Materials Research, Fuzhou University, Fuzhou 350108, China
  • [ 2 ] [Wei, Zong-Ping]Institute for Materials Research, Fuzhou University, Fuzhou 350108, China
  • [ 3 ] [Wang, Xin]Institute for Materials Research, Fuzhou University, Fuzhou 350108, China
  • [ 4 ] [Shao, Yan-Qun]Institute for Materials Research, Fuzhou University, Fuzhou 350108, China
  • [ 5 ] [Tang, Dian]Institute for Materials Research, Fuzhou University, Fuzhou 350108, China

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Source :

Chinese Journal of Nonferrous Metals

ISSN: 1004-0609

CN: 43-1238/TG

Year: 2011

Issue: 3

Volume: 21

Page: 669-674

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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