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Abstract:
An IrO2-Ta2O5/Ti anode coating with molar ratio of Ir to Ta of 7:3 on titanium was prepared by a modified technology, in which a portion of nano-crystalline of IrO2 was introduced to replace some amount of H2IrCl6 in the precursor solution. The phase structure and morphology of the coating were analyzed by X-ray diffractometry (XRD) and scanning electronic microscopy (SEM), respectively. The electro-catalytic properties and electrochemical stability of the coating were also characterized by using O2 evolution polarization, cyclic voltammetry (CV) test and accelerating-life test, respectively. The results show that the crystallite phases of the nano-seeds embedded electrode coating are IrO2-based solid solution (Ir, Ta)O2 and IrO2 phase. In addition, the anodes with the nano-seeds embedded coatings exhibit better electro-catalytic activity and corrosion resistance compared with the IrO2-Ta2O5/Ti anodes prepared by the traditional method.
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Chinese Journal of Nonferrous Metals
ISSN: 1004-0609
CN: 43-1238/TG
Year: 2011
Issue: 3
Volume: 21
Page: 669-674
Cited Count:
WoS CC Cited Count: 0
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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