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author:

Bai, S.-J. (Bai, S.-J..) [1] | Wei, Z.-P. (Wei, Z.-P..) [2] | Wang, X. (Wang, X..) [3] | Shao, Y.-Q. (Shao, Y.-Q..) [4] | Tang, D. (Tang, D..) [5]

Indexed by:

Scopus PKU CSCD

Abstract:

An IrO2-Ta2O5/Ti anode coating with molar ratio of Ir to Ta of 7:3 on titanium was prepared by a modified technology, in which a portion of nano-crystalline of IrO2 was introduced to replace some amount of H2IrCl6 in the precursor solution. The phase structure and morphology of the coating were analyzed by X-ray diffractometry (XRD) and scanning electronic microscopy (SEM), respectively. The electro-catalytic properties and electrochemical stability of the coating were also characterized by using O2 evolution polarization, cyclic voltammetry (CV) test and accelerating-life test, respectively. The results show that the crystallite phases of the nano-seeds embedded electrode coating are IrO2-based solid solution (Ir, Ta)O2 and IrO2 phase. In addition, the anodes with the nano-seeds embedded coatings exhibit better electro-catalytic activity and corrosion resistance compared with the IrO2-Ta2O5/Ti anodes prepared by the traditional method.

Keyword:

Electro-catalytic properties; IrO2; Nano-seeds; Ta2O5; Titanium anode

Community:

  • [ 1 ] [Bai, S.-J.]Institute for Materials Research, Fuzhou University, Fuzhou 350108, China
  • [ 2 ] [Wei, Z.-P.]Institute for Materials Research, Fuzhou University, Fuzhou 350108, China
  • [ 3 ] [Wang, X.]Institute for Materials Research, Fuzhou University, Fuzhou 350108, China
  • [ 4 ] [Shao, Y.-Q.]Institute for Materials Research, Fuzhou University, Fuzhou 350108, China
  • [ 5 ] [Tang, D.]Institute for Materials Research, Fuzhou University, Fuzhou 350108, China

Reprint 's Address:

  • [Wang, X.]Institute for Materials Research, Fuzhou University, Fuzhou 350108, China

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Source :

Chinese Journal of Nonferrous Metals

ISSN: 1004-0609

Year: 2011

Issue: 3

Volume: 21

Page: 669-674

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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