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Abstract:
In order to obtain a high specific capacitance, Ti/Ir0.4Sn0.6O2 electrodes were prepared by thermal decomposition. The structure, surface morphology and electrochemical properties of the Ti/Ir0.4Sn0.6O2 electrodes were investigated by X-ray diffraction (XRD), thermal analysis, scanning electron microscopy (SEM) and cyclic voltammetry (CV). The results show that the crystallization temperature of Ti/Ir0.4Sn0.6O2 electrode material is up to 360°C. Many small white particles on the electrode surface which are mainly composed of active oxide can be observed when it is annealed at 320°C. The specific capacitance is greatly affected by annealing temperature. The value of capacitance is small and its reversibility is very poor when the annealing temperature is 280°C. The maximum value of specific capacitance of the electrode annealed at 320°C is 454 F/g. The specific capacitance increases as the charge-discharge cycle count is increased. After 9000 cycles, the specific capacitance just starts to decrease. Even after 10000 cycles, it is still maintained 10% higher than that of the first cycle and the value is 493 F/g.
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Transactions of Materials and Heat Treatment
ISSN: 1009-6264
CN: 11-4545/TG
Year: 2012
Issue: 2
Volume: 33
Page: 17-20
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 3
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