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author:

Zhu, Jun-Qiu (Zhu, Jun-Qiu.) [1] | Wang, Xin (Wang, Xin.) [2] (Scholars:王欣) | Lu, Heng-Da (Lu, Heng-Da.) [3] | Shao, Yan-Qun (Shao, Yan-Qun.) [4] (Scholars:邵艳群) | Zhang, Teng (Zhang, Teng.) [5] | Tang, Dian (Tang, Dian.) [6] (Scholars:唐电)

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Abstract:

A amorphous/crystal mixed structural 36% RuO2-64% Ta2O5 coating was deposited on titanium substrate from ethanol ruthenium and tantalum chloride solution, using the thermal decomposition method at 300°C.Structure and electrochemical capacitive properties of the coating were investigated by means of X-ray diffraction(XRD), scanning electron microscopy(SEM), cyclic voltammetry(CV) and galvanostatic charge-discharge tests. The XRD results reveal the 36% RuO2-64% Ta2O5 coating presents amorphous structure with some nano-size crystallites in the amorphous matrix. The electrochemical analysis shows that the Ti/36% RuO2-64% Ta2O5 electrode exhibits typical capacitive characteristics and good power characteristics in 0.5 mol/L H2SO4 electrolyte. Its specific capacitance as single electrode is up to 525.5 and 495.1 F/g(RuO2) at a discharge current of 5 and 10 mA/cm2, respectively. Excellent cycling behavior is observed for this coating, with no loss in specific capacitance during 2000 cycles.

Keyword:

Capacitance Chlorine compounds Coatings Cyclic voltammetry Decomposition Electrochemical electrodes Ethanol Ruthenium Ruthenium alloys Ruthenium compounds Scanning electron microscopy Tantalum Tantalum oxides X ray diffraction

Community:

  • [ 1 ] [Zhu, Jun-Qiu]College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 2 ] [Wang, Xin]College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 3 ] [Lu, Heng-Da]College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 4 ] [Shao, Yan-Qun]College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 5 ] [Zhang, Teng]Institute for Materials Research, Fuzhou University, Fuzhou 350108, China
  • [ 6 ] [Tang, Dian]Institute for Materials Research, Fuzhou University, Fuzhou 350108, China

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Source :

Transactions of Materials and Heat Treatment

ISSN: 1009-6264

CN: 11-4545/TG

Year: 2012

Issue: 7

Volume: 33

Page: 122-126

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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