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Abstract:
A platinum coated heated pencil graphite electrode (Pt/HPGE) was fabricated and its properties were characterized by cyclic voltammetry (CV) and scanning electron microscopy (SEM), etc. It was demonstrated that Pt/HPGE had unique properties such as cheapness, easy preparation, good reproducibility and sensitive temperature response. The Pt/HPGE was employed to detect riboflavin (RF) sensitively based on the quenching effect of RF on Ru(bpy)(3)(2+)/C2O42- electrochemiluminescence (ECL) system. The limit of detection was 1. 9 x 10(-10) mol/L (S/N=3) at an electrode temperature of 58 degrees C, which clearly lower than that at room temperature. The method was applied to the determination of RF in vitamin pills with an average recovery of 102. 8%.
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CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
ISSN: 0253-3820
CN: 22-1125/O6
Year: 2011
Issue: 12
Volume: 39
Page: 1898-1902
0 . 9 4 1
JCR@2011
1 . 2 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:4
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 1
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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