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author:

Wu Ai-Hong (Wu Ai-Hong.) [1] | Sun Jian-Jun (Sun Jian-Jun.) [2] (Scholars:孙建军) | Wu Shao-Hua (Wu Shao-Hua.) [3] (Scholars:吴韶华)

Indexed by:

SCIE PKU CSCD

Abstract:

A platinum coated heated pencil graphite electrode (Pt/HPGE) was fabricated and its properties were characterized by cyclic voltammetry (CV) and scanning electron microscopy (SEM), etc. It was demonstrated that Pt/HPGE had unique properties such as cheapness, easy preparation, good reproducibility and sensitive temperature response. The Pt/HPGE was employed to detect riboflavin (RF) sensitively based on the quenching effect of RF on Ru(bpy)(3)(2+)/C2O42- electrochemiluminescence (ECL) system. The limit of detection was 1. 9 x 10(-10) mol/L (S/N=3) at an electrode temperature of 58 degrees C, which clearly lower than that at room temperature. The method was applied to the determination of RF in vitamin pills with an average recovery of 102. 8%.

Keyword:

Electrochemiluminescence Heated electrode Pencil graphite Platinum coating Riboflavin

Community:

  • [ 1 ] [Wu Ai-Hong]Fuzhou Univ, Coll Chem & Chem Engn, Minist Educ, Key Lab Anal & Detect Technol Food Safety, Fuzhou 350002, Peoples R China
  • [ 2 ] [Sun Jian-Jun]Fuzhou Univ, Coll Chem & Chem Engn, Minist Educ, Key Lab Anal & Detect Technol Food Safety, Fuzhou 350002, Peoples R China
  • [ 3 ] [Wu Shao-Hua]Fuzhou Univ, Coll Chem & Chem Engn, Minist Educ, Key Lab Anal & Detect Technol Food Safety, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 孙建军

    [Sun Jian-Jun]Fuzhou Univ, Coll Chem & Chem Engn, Minist Educ, Key Lab Anal & Detect Technol Food Safety, Fuzhou 350002, Peoples R China

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Source :

CHINESE JOURNAL OF ANALYTICAL CHEMISTRY

ISSN: 0253-3820

CN: 22-1125/O6

Year: 2011

Issue: 12

Volume: 39

Page: 1898-1902

0 . 9 4 1

JCR@2011

1 . 2 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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