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author:

Chen, Jialin (Chen, Jialin.) [1] | Zou, Qi (Zou, Qi.) [2] | Zeng, Fanrong (Zeng, Fanrong.) [3] | Wang, Shaorong (Wang, Shaorong.) [4] | Tang, Dian (Tang, Dian.) [5] (Scholars:唐电) | Yang, Hsiwen (Yang, Hsiwen.) [6] | Zhang, Teng (Zhang, Teng.) [7]

Indexed by:

EI Scopus SCIE

Abstract:

In this paper, TiO2 is added to CaO-SrO-B2O3-SiO2 sealing system to tailor the sealing properties of glass-ceramic seals. The coefficient of thermal expansion (CTE) of quenched glasses and glass-ceramics (held at 750 degrees C for 100 h) does not change significantly with the addition of TiO2; whereas, the glass stability (Delta T-xg = T-x - T-g) decreases systematically with increasing TiO2. The addition of TiO2 accelerates the crystallization of sealing glasses. The formation of Sr-containing phase, e.g., Sr(TiO3), contributes to the improved chemical compatibility as well as the increase in conductivity of sealing glasses (e.g., from 7.9 x 10(-8) S cm(-1) to 6.9 x 10(-5) S cm(-1) at 800 degrees C). In addition, the good bonding is observed at the interface between Cr-containing interconnect (430SS) and glasses containing 4-8 mole % TiO2, held at 750 degrees C for 100 h. (C) 2013 Elsevier B.V. All rights reserved.

Keyword:

Crystallization Glass-ceramic seals Sealing properties Solid oxide fuel cells

Community:

  • [ 1 ] [Chen, Jialin]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Zou, Qi]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Tang, Dian]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Zhang, Teng]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 5 ] [Zeng, Fanrong]Chinese Acad Sci SICCAS, Shanghai Inst Ceram, CAS Key Lab Mat Energy Convers, Shanghai 200050, Peoples R China
  • [ 6 ] [Wang, Shaorong]Chinese Acad Sci SICCAS, Shanghai Inst Ceram, CAS Key Lab Mat Energy Convers, Shanghai 200050, Peoples R China
  • [ 7 ] [Yang, Hsiwen]Natl United Univ, Dept Mat Sci & Engn, Miaoli 36003, Taiwan

Reprint 's Address:

  • 张腾

    [Zhang, Teng]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China

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Source :

JOURNAL OF POWER SOURCES

ISSN: 0378-7753

Year: 2013

Volume: 241

Page: 578-582

5 . 2 1 1

JCR@2013

8 . 1 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 19

SCOPUS Cited Count: 19

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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