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Thermally induced crystallization in sealing glass is one of the main factors in affecting their application in intermediate-temperature solid oxide fuel cells (IT-SOFCs). Herein, the influence of crystallization on the physical properties and sealing ability of BaO-MgO-Al2O3-B2O3-SiO2 (BMABS) glass are investigated. The results show that crystal phases, BaAl2Si2O8, BaMg2Si2O7, and Ba5Si8O21 are readily precipitated from the glass at a preannealing temperature of 750 degrees C, and the crystallinity reaches 44 % and 58 % after pre-annealing for 20 h and 100 h, respectively. Nevertheless, the physical properties of the pre-annealed BMABS glass fall into the requirements for IT-SOFCs. After pre-annealing at 750 degrees C for 100 h, the coefficient of thermal expansion of BMABS is 10.7 x 10-6 K-1, the electrical conductivity is 3.2 x 10- 7 S cm- 1 at 750 degrees C, and the self-healing ability is maintained. Moreover, the utilization of a stainless steel | BMABS glass | single cell sandwiched assembly assessment demonstrates excellent gas-tightness and intact sealing interfaces between the BMABS glass and adjacent components.
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CERAMICS INTERNATIONAL
ISSN: 0272-8842
Year: 2025
Issue: 11
Volume: 51
Page: 14723-14729
5 . 1 0 0
JCR@2023
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