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author:

Zheng, Jiayong (Zheng, Jiayong.) [1] | Lu, Zhenghao (Lu, Zhenghao.) [2] | Chen, Zhiyi (Chen, Zhiyi.) [3] | Ai, Na (Ai, Na.) [4] | Guan, Chengzhi (Guan, Chengzhi.) [5] | Wang, Xin (Wang, Xin.) [6] | Shao, Yanqun (Shao, Yanqun.) [7] | Jiang, San Ping (Jiang, San Ping.) [8] | Chen, Kongfa (Chen, Kongfa.) [9]

Indexed by:

SCIE

Abstract:

Thermally induced crystallization in sealing glass is one of the main factors in affecting their application in intermediate-temperature solid oxide fuel cells (IT-SOFCs). Herein, the influence of crystallization on the physical properties and sealing ability of BaO-MgO-Al2O3-B2O3-SiO2 (BMABS) glass are investigated. The results show that crystal phases, BaAl2Si2O8, BaMg2Si2O7, and Ba5Si8O21 are readily precipitated from the glass at a preannealing temperature of 750 degrees C, and the crystallinity reaches 44 % and 58 % after pre-annealing for 20 h and 100 h, respectively. Nevertheless, the physical properties of the pre-annealed BMABS glass fall into the requirements for IT-SOFCs. After pre-annealing at 750 degrees C for 100 h, the coefficient of thermal expansion of BMABS is 10.7 x 10-6 K-1, the electrical conductivity is 3.2 x 10- 7 S cm- 1 at 750 degrees C, and the self-healing ability is maintained. Moreover, the utilization of a stainless steel | BMABS glass | single cell sandwiched assembly assessment demonstrates excellent gas-tightness and intact sealing interfaces between the BMABS glass and adjacent components.

Keyword:

Crystallization Sealing glass Solid oxide fuel cells Thermal stability

Community:

  • [ 1 ] [Zheng, Jiayong]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Lu, Zhenghao]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Chen, Zhiyi]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Wang, Xin]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 5 ] [Shao, Yanqun]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 6 ] [Chen, Kongfa]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 7 ] [Ai, Na]Fuzhou Univ, Fujian Coll Assoc Instrumental Anal Ctr, Fuzhou 350108, Fujian, Peoples R China
  • [ 8 ] [Guan, Chengzhi]Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Shanghai 201800, Peoples R China
  • [ 9 ] [Jiang, San Ping]Foshan Xianhu Lab, Natl Energy Key Lab New Hydrogen Ammonia Energy Te, Foshan 528216, Peoples R China
  • [ 10 ] [Jiang, San Ping]Curtin Univ, WA Sch Mines Minerals Energy & Chem Engn, Perth, WA 6102, Australia

Reprint 's Address:

  • [Chen, Kongfa]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China

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Source :

CERAMICS INTERNATIONAL

ISSN: 0272-8842

Year: 2025

Issue: 11

Volume: 51

Page: 14723-14729

5 . 1 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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