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[期刊论文]

Tailoring the sealing properties of TiO2-CaO-SrO-B 2O3-SiO2 glass-ceramic seals: Thermal properties, chemical compatibility and electrical property

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author:

Chen, Jialin (Chen, Jialin.) [1] | Zou, Qi (Zou, Qi.) [2] | Zeng, Fanrong (Zeng, Fanrong.) [3] | Unfold

Indexed by:

EI

Abstract:

In this paper, TiO2 is added to CaO-SrO-B2O 3-SiO2 sealing system to tailor the sealing properties of glass-ceramic seals. The coefficient of thermal expansion (CTE) of quenched glasses and glass-ceramics (held at 750 C for 100 h) does not change significantly with the addition of TiO2; whereas, the glass stability (ΔTxg = Tx - Tg) decreases systematically with increasing TiO2. The addition of TiO2 accelerates the crystallization of sealing glasses. The formation of Sr-containing phase, e.g., Sr(TiO3), contributes to the improved chemical compatibility as well as the increase in conductivity of sealing glasses (e.g., from 7.9 × 10-8 S cm-1 to 6.9 × 10-5 S cm-1 at 800 C). In addition, the good bonding is observed at the interface between Cr-containing interconnect (430SS) and glasses containing 4-8 mole % TiO2, held at 750 C for 100 h. © 2013 Elsevier B.V. All rights reserved.

Keyword:

Chemical bonds C (programming language) Crystallization Glass ceramics Seals Silica Solid oxide fuel cells (SOFC) Strontium compounds Thermal expansion Titanium dioxide

Community:

  • [ 1 ] [Chen, Jialin]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
  • [ 2 ] [Zou, Qi]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
  • [ 3 ] [Zeng, Fanrong]CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS), 1295 Dingxi Road, Shanghai 200050, China
  • [ 4 ] [Wang, Shaorong]CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS), 1295 Dingxi Road, Shanghai 200050, China
  • [ 5 ] [Tang, Dian]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
  • [ 6 ] [Yang, Hsiwen]Department of Materials Science and Engineering, National United University, Miao-Li 36003, Taiwan
  • [ 7 ] [Zhang, Teng]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian 350108, China

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Source :

Journal of Power Sources

ISSN: 0378-7753

Year: 2013

Volume: 241

Page: 578-582

5 . 2 1 1

JCR@2013

8 . 1 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 19

30 Days PV: 0

Affiliated Colleges:

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