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author:

Long, Bo (Long, Bo.) [1] | Cheng, Shuying (Cheng, Shuying.) [2] (Scholars:程树英) | Lai, Yunfeng (Lai, Yunfeng.) [3] (Scholars:赖云锋) | Zhou, Haifang (Zhou, Haifang.) [4] (Scholars:周海芳) | Yu, Jinling (Yu, Jinling.) [5] (Scholars:俞金玲) | Zheng, Qiao (Zheng, Qiao.) [6] (Scholars:郑巧)

Indexed by:

EI Scopus SCIE

Abstract:

Cu2ZnSnS4 (CZTS) thin films were prepared by sol-gel method and sulfurization process. The effects of the sulfurization temperature on the structural, morphological, compositional, and opto-electrical properties of the CZTS films were investigated. X-ray diffraction and Raman spectroscopy analyses confirmed the formation of CZTS films. With increasing sulfurization temperature, the crystallinity of the films was enhanced, which was accompanied by metallic deficiency, especially tin loss. When the sulfurization temperature was increased from 460 to 540 degrees C, the optical band-gap value decreased from 1.63 to 1.38 eV, while the resistivity and mobility increased from1.415 to 1313 Omega.cm and from 0.372 to 7.231 cm(2)/V.s, respectively. The best CZTS film properties with a bandgap of 1.47 eV, resistivity of 581.5 Omega.cm, carrier concentration of 2.165 x 10(16) cm(-3) and mobility of 1.411 cm(2)/(V.s) were achieved at a sulfurization temperature of 500 degrees C, and make the films suitable as absorbers for solar cells. (C) 2014 Elsevier B.V. All rights reserved.

Keyword:

Copper zinc tin sulfide Electrical properties Optical properties Sol-gel deposition Sulfurization Temperature Thin film

Community:

  • [ 1 ] [Long, Bo]Fuzhou Univ, Coll Phys & Informat Engn, Inst Micronano Devices Solar Cells, Fuzhou 350108, Peoples R China
  • [ 2 ] [Cheng, Shuying]Fuzhou Univ, Coll Phys & Informat Engn, Inst Micronano Devices Solar Cells, Fuzhou 350108, Peoples R China
  • [ 3 ] [Lai, Yunfeng]Fuzhou Univ, Coll Phys & Informat Engn, Inst Micronano Devices Solar Cells, Fuzhou 350108, Peoples R China
  • [ 4 ] [Zhou, Haifang]Fuzhou Univ, Coll Phys & Informat Engn, Inst Micronano Devices Solar Cells, Fuzhou 350108, Peoples R China
  • [ 5 ] [Yu, Jinling]Fuzhou Univ, Coll Phys & Informat Engn, Inst Micronano Devices Solar Cells, Fuzhou 350108, Peoples R China
  • [ 6 ] [Zheng, Qiao]Fuzhou Univ, Coll Phys & Informat Engn, Inst Micronano Devices Solar Cells, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • 程树英

    [Cheng, Shuying]Fuzhou Univ, Coll Phys & Informat Engn, Inst Micronano Devices Solar Cells, Fuzhou 350108, Peoples R China

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Source :

THIN SOLID FILMS

ISSN: 0040-6090

Year: 2014

Volume: 573

Page: 117-121

1 . 7 5 9

JCR@2014

2 . 0 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:355

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 32

SCOPUS Cited Count: 35

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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