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Abstract:
Cu2SnS3 (CTS) thin films were grown by sulfurization of vacuum thermal evaporated Sn-Cu metallic precursors in a H2S:N-2 atmosphere. Different Cu/Sn composition ratios of the films were prepared to study the effect of Cu/Sn atomic ratio on the properties of the CTS thin films. The microstructures and Cu/Sn composition ratios of the films were characterized with X-ray diffraction and energy dispersive X-ray spectroscopy (EDS), respectively. The X-ray diffractograms show that the deposited films are exclusively oriented along the (111) direction. The optical absorption coefficient and band gap of the films were estimated by transmission and reflection spectra measured at room temperature. Highly crystallized p-type CTS thin films were achieved when the Cu/Sn ratio was about 2.0. They had high absorption coefficient of similar to 10(4) cm(-1), suitable carrier concentration similar to 10(17) cm(3), high mobility 10(0)cm(2)v(-1)s(-1) and narrow optical band gap similar to 0.9 eV. Therefore, CTS thin films are suitable as absorber materials of thin film solar cells.
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JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS
ISSN: 1454-4164
Year: 2016
Issue: 9-10
Volume: 18
Page: 863-867
0 . 4 4 9
JCR@2016
0 . 6 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:324
JCR Journal Grade:4
CAS Journal Grade:4
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SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
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