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In this study, graphitic carbon nitride supported platinum nanocomposites (g-C3N4/PtNPs) have been synthesized for the first time by an ultrasonic-assisted chemical reduction method. By using g-C3N4 as the stabilizer, Pt ions could be reduced to PtNPs by NaBH4 and uniformly deposited on the surface of g-C3N4. The resulting g-C3N4/PtNPs exhibited enhanced catalytic activity for the oxidation of 3,3 ',5,5 '-tetramethylbenzidine (TMB) compared to that of g-C3N4 or PtNPs alone. After interaction with Hg2+, the catalytic activity of g-C3N4/PtNPs was effectively inhibited due to the formation of HgPt amalgam. On the basis of this effect, a novel label free colorimetric sensor has been developed for sensitive detection of Hg2+ through the g-C3N4/PtNPs mediated catalytic reaction. A detection limit as low as 1.23 nM was achieved. This assay also exhibited excellent selectivity toward Hg2+ over other metal ions. In addition, it was successfully applied to the determination of Hg2+ in real water samples. In view of the advantages, such as simple operation, cost-effective, rapid response and naked-eye observation, the developed colorimetric sensor hold great potential for the detection of toxic Hg2+ in environmental and biological samples. (C) 2017 Elsevier B.V. All rights reserved.
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ANALYTICA CHIMICA ACTA
ISSN: 0003-2670
Year: 2017
Volume: 980
Page: 72-78
5 . 1 2 3
JCR@2017
5 . 7 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:226
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 47
SCOPUS Cited Count: 48
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 4
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