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author:

Wang, Yi-Wei (Wang, Yi-Wei.) [1] | Wang, Lixing (Wang, Lixing.) [2] | An, Fengping (An, Fengping.) [3] | Xu, Hui (Xu, Hui.) [4] | Yin, Zejin (Yin, Zejin.) [5] | Tang, Shurong (Tang, Shurong.) [6] | Yang, Huang-Hao (Yang, Huang-Hao.) [7] (Scholars:杨黄浩) | Song, Hongbo (Song, Hongbo.) [8]

Indexed by:

EI Scopus SCIE

Abstract:

In this study, graphitic carbon nitride supported platinum nanocomposites (g-C3N4/PtNPs) have been synthesized for the first time by an ultrasonic-assisted chemical reduction method. By using g-C3N4 as the stabilizer, Pt ions could be reduced to PtNPs by NaBH4 and uniformly deposited on the surface of g-C3N4. The resulting g-C3N4/PtNPs exhibited enhanced catalytic activity for the oxidation of 3,3 ',5,5 '-tetramethylbenzidine (TMB) compared to that of g-C3N4 or PtNPs alone. After interaction with Hg2+, the catalytic activity of g-C3N4/PtNPs was effectively inhibited due to the formation of HgPt amalgam. On the basis of this effect, a novel label free colorimetric sensor has been developed for sensitive detection of Hg2+ through the g-C3N4/PtNPs mediated catalytic reaction. A detection limit as low as 1.23 nM was achieved. This assay also exhibited excellent selectivity toward Hg2+ over other metal ions. In addition, it was successfully applied to the determination of Hg2+ in real water samples. In view of the advantages, such as simple operation, cost-effective, rapid response and naked-eye observation, the developed colorimetric sensor hold great potential for the detection of toxic Hg2+ in environmental and biological samples. (C) 2017 Elsevier B.V. All rights reserved.

Keyword:

Colorimetric sensor Graphitic carbon nitride/platinum Mercury ions nanocomposite

Community:

  • [ 1 ] [Wang, Yi-Wei]Fujian Agr & Forestry Univ, Coll Food Sci, Key Lab Predict Microbiol & Chem Residual Anal, Fuzhou 350002, Peoples R China
  • [ 2 ] [Wang, Lixing]Fujian Agr & Forestry Univ, Coll Food Sci, Key Lab Predict Microbiol & Chem Residual Anal, Fuzhou 350002, Peoples R China
  • [ 3 ] [An, Fengping]Fujian Agr & Forestry Univ, Coll Food Sci, Key Lab Predict Microbiol & Chem Residual Anal, Fuzhou 350002, Peoples R China
  • [ 4 ] [Xu, Hui]Fujian Agr & Forestry Univ, Coll Food Sci, Key Lab Predict Microbiol & Chem Residual Anal, Fuzhou 350002, Peoples R China
  • [ 5 ] [Song, Hongbo]Fujian Agr & Forestry Univ, Coll Food Sci, Key Lab Predict Microbiol & Chem Residual Anal, Fuzhou 350002, Peoples R China
  • [ 6 ] [Yin, Zejin]Fujian Med Univ, Dept Pharmaceut Anal, Fac Pharm, Fuzhou 350108, Fujian, Peoples R China
  • [ 7 ] [Tang, Shurong]Fujian Med Univ, Dept Pharmaceut Anal, Fac Pharm, Fuzhou 350108, Fujian, Peoples R China
  • [ 8 ] [Yang, Huang-Hao]Fuzhou Univ, Coll Chem, Key Lab Anal & Detect Technol Food Safety MOE, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • 杨黄浩

    [Song, Hongbo]Fujian Agr & Forestry Univ, Coll Food Sci, Key Lab Predict Microbiol & Chem Residual Anal, Fuzhou 350002, Peoples R China;;[Tang, Shurong]Fujian Med Univ, Dept Pharmaceut Anal, Fac Pharm, Fuzhou 350108, Fujian, Peoples R China;;[Yang, Huang-Hao]Fuzhou Univ, Coll Chem, Key Lab Anal & Detect Technol Food Safety MOE, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China

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Source :

ANALYTICA CHIMICA ACTA

ISSN: 0003-2670

Year: 2017

Volume: 980

Page: 72-78

5 . 1 2 3

JCR@2017

5 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:226

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 47

SCOPUS Cited Count: 48

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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