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author:

Wang, Y.-W. (Wang, Y.-W..) [1] | Wang, L. (Wang, L..) [2] | An, F. (An, F..) [3] | Xu, H. (Xu, H..) [4] | Yin, Z. (Yin, Z..) [5] | Tang, S. (Tang, S..) [6] | Yang, H.-H. (Yang, H.-H..) [7] | Song, H. (Song, H..) [8]

Indexed by:

Scopus

Abstract:

In this study, graphitic carbon nitride supported platinum nanocomposites (g-C3N4/PtNPs) have been synthesized for the first time by an ultrasonic-assisted chemical reduction method. By using g-C3N4 as the stabilizer, Pt ions could be reduced to PtNPs by NaBH4 and uniformly deposited on the surface of g-C3N4. The resulting g-C3N4/PtNPs exhibited enhanced catalytic activity for the oxidation of 3,3′,5,5’-tetramethylbenzidine (TMB) compared to that of g-C3N4 or PtNPs alone. After interaction with Hg2+, the catalytic activity of g-C3N4/PtNPs was effectively inhibited due to the formation of HgPt amalgam. On the basis of this effect, a novel label free colorimetric sensor has been developed for sensitive detection of Hg2+ through the g-C3N4/PtNPs mediated catalytic reaction. A detection limit as low as 1.23 nM was achieved. This assay also exhibited excellent selectivity toward Hg2+ over other metal ions. In addition, it was successfully applied to the determination of Hg2+ in real water samples. In view of the advantages, such as simple operation, cost-effective, rapid response and naked-eye observation, the developed colorimetric sensor hold great potential for the detection of toxic Hg2+ in environmental and biological samples. © 2017 Elsevier B.V.

Keyword:

Colorimetric sensor; Graphitic carbon nitride/platinum nanocomposite; Mercury ions

Community:

  • [ 1 ] [Wang, Y.-W.]Key Laboratory of Predictive Microbiology and Chemical Residual Analysis, College of Food Science, Fujian Agriculture and Forestry University, Fuzhou, 350002, China
  • [ 2 ] [Wang, L.]Key Laboratory of Predictive Microbiology and Chemical Residual Analysis, College of Food Science, Fujian Agriculture and Forestry University, Fuzhou, 350002, China
  • [ 3 ] [An, F.]Key Laboratory of Predictive Microbiology and Chemical Residual Analysis, College of Food Science, Fujian Agriculture and Forestry University, Fuzhou, 350002, China
  • [ 4 ] [Xu, H.]Key Laboratory of Predictive Microbiology and Chemical Residual Analysis, College of Food Science, Fujian Agriculture and Forestry University, Fuzhou, 350002, China
  • [ 5 ] [Yin, Z.]Department of Pharmaceutical Analysis, Faculty of Pharmacy, Fujian Medical University, Fuzhou, Fujian 350108, China
  • [ 6 ] [Tang, S.]Department of Pharmaceutical Analysis, Faculty of Pharmacy, Fujian Medical University, Fuzhou, Fujian 350108, China
  • [ 7 ] [Yang, H.-H.]The Key Lab of Analysis and Detection Technology for Food Safety of the MOE, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
  • [ 8 ] [Song, H.]Key Laboratory of Predictive Microbiology and Chemical Residual Analysis, College of Food Science, Fujian Agriculture and Forestry University, Fuzhou, 350002, China

Reprint 's Address:

  • [Tang, S.]Department of Pharmaceutical Analysis, Faculty of Pharmacy, Fujian Medical UniversityChina

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Source :

Analytica Chimica Acta

ISSN: 0003-2670

Year: 2017

Volume: 980

Page: 72-78

5 . 1 2 3

JCR@2017

5 . 7 0 0

JCR@2023

ESI HC Threshold:226

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 48

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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