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author:

Wang, Yi-Wei (Wang, Yi-Wei.) [1] | Wang, Lixing (Wang, Lixing.) [2] | An, Fengping (An, Fengping.) [3] | Xu, Hui (Xu, Hui.) [4] | Yin, Zejin (Yin, Zejin.) [5] | Tang, Shurong (Tang, Shurong.) [6] | Yang, Huang-Hao (Yang, Huang-Hao.) [7] | Song, Hongbo (Song, Hongbo.) [8]

Indexed by:

EI

Abstract:

In this study, graphitic carbon nitride supported platinum nanocomposites (g-C3N4/PtNPs) have been synthesized for the first time by an ultrasonic-assisted chemical reduction method. By using g-C3N4 as the stabilizer, Pt ions could be reduced to PtNPs by NaBH4 and uniformly deposited on the surface of g-C3N4. The resulting g-C3N4/PtNPs exhibited enhanced catalytic activity for the oxidation of 3,3′,5,5’-tetramethylbenzidine (TMB) compared to that of g-C3N4 or PtNPs alone. After interaction with Hg2+, the catalytic activity of g-C3N4/PtNPs was effectively inhibited due to the formation of HgPt amalgam. On the basis of this effect, a novel label free colorimetric sensor has been developed for sensitive detection of Hg2+ through the g-C3N4/PtNPs mediated catalytic reaction. A detection limit as low as 1.23 nM was achieved. This assay also exhibited excellent selectivity toward Hg2+ over other metal ions. In addition, it was successfully applied to the determination of Hg2+ in real water samples. In view of the advantages, such as simple operation, cost-effective, rapid response and naked-eye observation, the developed colorimetric sensor hold great potential for the detection of toxic Hg2+ in environmental and biological samples. © 2017 Elsevier B.V.

Keyword:

Binary alloys Carbon nitride Catalysis Catalyst activity Catalytic oxidation Color Colorimetry Cost effectiveness Mercury amalgams Metal ions Nanocomposites Nitrides Platinum Sodium Borohydride Ultrasonic applications

Community:

  • [ 1 ] [Wang, Yi-Wei]Key Laboratory of Predictive Microbiology and Chemical Residual Analysis, College of Food Science, Fujian Agriculture and Forestry University, Fuzhou; 350002, China
  • [ 2 ] [Wang, Lixing]Key Laboratory of Predictive Microbiology and Chemical Residual Analysis, College of Food Science, Fujian Agriculture and Forestry University, Fuzhou; 350002, China
  • [ 3 ] [An, Fengping]Key Laboratory of Predictive Microbiology and Chemical Residual Analysis, College of Food Science, Fujian Agriculture and Forestry University, Fuzhou; 350002, China
  • [ 4 ] [Xu, Hui]Key Laboratory of Predictive Microbiology and Chemical Residual Analysis, College of Food Science, Fujian Agriculture and Forestry University, Fuzhou; 350002, China
  • [ 5 ] [Yin, Zejin]Department of Pharmaceutical Analysis, Faculty of Pharmacy, Fujian Medical University, Fuzhou; Fujian; 350108, China
  • [ 6 ] [Tang, Shurong]Department of Pharmaceutical Analysis, Faculty of Pharmacy, Fujian Medical University, Fuzhou; Fujian; 350108, China
  • [ 7 ] [Yang, Huang-Hao]The Key Lab of Analysis and Detection Technology for Food Safety of the MOE, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou; 350108, China
  • [ 8 ] [Song, Hongbo]Key Laboratory of Predictive Microbiology and Chemical Residual Analysis, College of Food Science, Fujian Agriculture and Forestry University, Fuzhou; 350002, China

Reprint 's Address:

  • [tang, shurong]department of pharmaceutical analysis, faculty of pharmacy, fujian medical university, fuzhou; fujian; 350108, china

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Source :

Analytica Chimica Acta

ISSN: 0003-2670

Year: 2017

Volume: 980

Page: 72-78

5 . 1 2 3

JCR@2017

5 . 7 0 0

JCR@2023

ESI HC Threshold:226

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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