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author:

Weng, Yajie (Weng, Yajie.) [1] | Lai, Hanjiang (Lai, Hanjiang.) [2] | Zheng, Junjie (Zheng, Junjie.) [3] | Cui, Mingjuan (Cui, Mingjuan.) [4] | Chen, Yihang (Chen, Yihang.) [5] | Xu, Zhitao (Xu, Zhitao.) [6] | Jiang, Wensong (Jiang, Wensong.) [7] | Zhang, Jianwei (Zhang, Jianwei.) [8] | Song, Yu (Song, Yu.) [9]

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SCIE

Abstract:

The one-phase-low-pH method is a simple, efficient, and user-friendly biogrouting technique that can effectively improve the biomineralization of enzyme-induced carbonate precipitation (EICP) using free urease enzyme. One of the most significant advantages of this method is its capacity to effectively delay calcium carbonate (CaCO3) precipitation by reducing the pH of the solution through the addition of acid. This prevents bioclogging during the biogrouting process and improves the biomineralization effect. However, the biomineralization of the one-phase-low-pH based EICP method may be influenced by the specific acid used. To investigate the impact of acid type on the one-phase-low-pH EICP method using crude soybean urease solution (CSUS), four types of acids, including hydrochloric acid (HCl), nitric acid (HNO3), acetic acid (CH3COOH), and lactic acid (C3H6O3), were used to adjust the pH of CSUS. A series of macroscopic and microscopic experiments were conducted to evaluate the effect of acid type on the onephase-low-pH EICP method. The results indicate that the acid has an inhibition on the urease activity (UA) of CSUS. Among the acids tested, HNO3 exhibits the most pronounced inhibitory effect on the UA of CSUS, followed by HCl, and the least pronounced inhibitory effect for CH3COOH and C3H6O3 under the same pH conditions. Meanwhile, CH3COOH and C3H6O3 could provide a longer delay duration of CaCO3 precipitation than HNO3 and HCl. Therefore, the one-phase-low-pH EICP method based on CH3COOH and C3H6O3 can significantly improve the effective biocementation depth compared to that based on HNO3 and HCl. Nevertheless, the different types of acids appear to have no obvious effect on the polymorph and crystalline of the precipitated CaCO3 crystals. (c) 2024 Institute of Rock and Soil Mechanics, Chinese Academy of Sciences. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/ 4.0/).

Keyword:

Acid type Biomineralization Crude soybean urease solution (CSUS) (EICP) Enzyme-induced carbonate precipitation One-phase-low-pH method

Community:

  • [ 1 ] [Weng, Yajie]Huazhong Univ Sci & Technol, Sch Civil & Hydraul Engn, Wuhan 430074, Peoples R China
  • [ 2 ] [Zheng, Junjie]Huazhong Univ Sci & Technol, Sch Civil & Hydraul Engn, Wuhan 430074, Peoples R China
  • [ 3 ] [Chen, Yihang]Huazhong Univ Sci & Technol, Sch Civil & Hydraul Engn, Wuhan 430074, Peoples R China
  • [ 4 ] [Xu, Zhitao]Huazhong Univ Sci & Technol, Sch Civil & Hydraul Engn, Wuhan 430074, Peoples R China
  • [ 5 ] [Jiang, Wensong]Huazhong Univ Sci & Technol, Sch Civil & Hydraul Engn, Wuhan 430074, Peoples R China
  • [ 6 ] [Lai, Hanjiang]Fuzhou Univ, Zijin Sch Geol & Min, Fuzhou 350108, Peoples R China
  • [ 7 ] [Zheng, Junjie]Wuhan Univ, Sch Civil Engn, Wuhan 430072, Peoples R China
  • [ 8 ] [Cui, Mingjuan]Fuzhou Univ, Coll Civil Engn, Fuzhou 350116, Peoples R China
  • [ 9 ] [Zhang, Jianwei]Henan Univ, Sch Civil & Architecture Engn, Kaifeng 475004, Peoples R China
  • [ 10 ] [Song, Yu]Guilin Univ Technol, Sch Civil Engn, Guilin 541006, Peoples R China

Reprint 's Address:

  • [Zheng, Junjie]Huazhong Univ Sci & Technol, Sch Civil & Hydraul Engn, Wuhan 430074, Peoples R China

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Source :

JOURNAL OF ROCK MECHANICS AND GEOTECHNICAL ENGINEERING

ISSN: 1674-7755

Year: 2024

Issue: 12

Volume: 16

Page: 5135-5146

9 . 4 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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