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Rare earth luminescent materials demonstrate significant advantages in lighting and energy saving, and detection etc. In this paper, a series of Ca2Ga2(Ge1-xSix)O-7:y%Eu2+ phosphors were synthesized by high-temperature solid-state reaction and characterized by X-ray diffraction and luminescence spectroscopy methods. The powder X-ray diffraction patterns reveal that all the phosphors are isostructural with a space group of P4 over bar 21m. The excitation spectra of Ca2Ga2(Ge1-xSix)O-7:1%Eu2+ phosphors exhibit significant overlapping of the host and the Eu2+ absorption bands, which facilitates Eu2+ absorbing the energy to increase its luminescence efficiency when excited by visible photons. The emission spectra show that the Eu2+ doped phosphors have a broad emission band with a peak centered at 510 nm arising from the 4f(6)5d(1)-> 4f(7) transition. Variable temperature fluorescence reveals that the phosphor has a strong luminescence at low temperature but has a severe thermal quenching effect when temperature rises. The optimal Ca2Ga2(Ge0.5Si0.5)O-7:1.0%Eu2+ phosphor shows promise for application in the field of fingerprint identification based on the experimental results.
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MATERIALS
ISSN: 1996-1944
Year: 2023
Issue: 10
Volume: 16
3 . 1
JCR@2023
3 . 1 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:49
JCR Journal Grade:1
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 1
SCOPUS Cited Count: 2
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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