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author:

Kong, Xiangqian (Kong, Xiangqian.) [1] | Qiu, Zhihua (Qiu, Zhihua.) [2] | Wu, Lina (Wu, Lina.) [3] | Lei, Yunfei (Lei, Yunfei.) [4] | Chi, Lisheng (Chi, Lisheng.) [5]

Indexed by:

EI Scopus SCIE

Abstract:

Rare earth luminescent materials demonstrate significant advantages in lighting and energy saving, and detection etc. In this paper, a series of Ca2Ga2(Ge1-xSix)O-7:y%Eu2+ phosphors were synthesized by high-temperature solid-state reaction and characterized by X-ray diffraction and luminescence spectroscopy methods. The powder X-ray diffraction patterns reveal that all the phosphors are isostructural with a space group of P4 over bar 21m. The excitation spectra of Ca2Ga2(Ge1-xSix)O-7:1%Eu2+ phosphors exhibit significant overlapping of the host and the Eu2+ absorption bands, which facilitates Eu2+ absorbing the energy to increase its luminescence efficiency when excited by visible photons. The emission spectra show that the Eu2+ doped phosphors have a broad emission band with a peak centered at 510 nm arising from the 4f(6)5d(1)-> 4f(7) transition. Variable temperature fluorescence reveals that the phosphor has a strong luminescence at low temperature but has a severe thermal quenching effect when temperature rises. The optimal Ca2Ga2(Ge0.5Si0.5)O-7:1.0%Eu2+ phosphor shows promise for application in the field of fingerprint identification based on the experimental results.

Keyword:

Eu2+ high-temperature solid-state reaction luminescence property phosphor

Community:

  • [ 1 ] [Kong, Xiangqian]Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350116, Peoples R China
  • [ 2 ] [Lei, Yunfei]Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350116, Peoples R China
  • [ 3 ] [Kong, Xiangqian]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350116, Peoples R China
  • [ 4 ] [Qiu, Zhihua]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350116, Peoples R China
  • [ 5 ] [Wu, Lina]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350116, Peoples R China
  • [ 6 ] [Chi, Lisheng]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350116, Peoples R China
  • [ 7 ] [Kong, Xiangqian]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Fuel & Mat Clean Nucl Energy Syst, Fuzhou 350002, Peoples R China
  • [ 8 ] [Qiu, Zhihua]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Fuel & Mat Clean Nucl Energy Syst, Fuzhou 350002, Peoples R China
  • [ 9 ] [Wu, Lina]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Fuel & Mat Clean Nucl Energy Syst, Fuzhou 350002, Peoples R China
  • [ 10 ] [Chi, Lisheng]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Fuel & Mat Clean Nucl Energy Syst, Fuzhou 350002, Peoples R China
  • [ 11 ] [Wu, Lina]Fuzhou Univ, Coll Chem, Fuzhou 350116, Peoples R China

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Source :

MATERIALS

ISSN: 1996-1944

Year: 2023

Issue: 10

Volume: 16

3 . 1

JCR@2023

3 . 1 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:49

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

Online/Total:4/10050710
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