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author:

Kong, Xiangqian (Kong, Xiangqian.) [1] | Qiu, Zhihua (Qiu, Zhihua.) [2] | Wu, Lina (Wu, Lina.) [3] | Lei, Yunfei (Lei, Yunfei.) [4] | Chi, Lisheng (Chi, Lisheng.) [5]

Indexed by:

EI

Abstract:

Rare earth luminescent materials demonstrate significant advantages in lighting and energy saving, and detection etc. In this paper, a series of Ca2Ga2(Ge1-xSix)O7:y%Eu2+ phosphors were synthesized by high-temperature solid-state reaction and characterized by X-ray diffraction and luminescence spectroscopy methods. The powder X-ray diffraction patterns reveal that all the phosphors are isostructural with a space group of P (Formula presented.) 21m. The excitation spectra of Ca2Ga2(Ge1-xSix)O7:1%Eu2+ phosphors exhibit significant overlapping of the host and the Eu2+ absorption bands, which facilitates Eu2+ absorbing the energy to increase its luminescence efficiency when excited by visible photons. The emission spectra show that the Eu2+ doped phosphors have a broad emission band with a peak centered at 510 nm arising from the 4f65d1→4f7 transition. Variable temperature fluorescence reveals that the phosphor has a strong luminescence at low temperature but has a severe thermal quenching effect when temperature rises. The optimal Ca2Ga2(Ge0.5Si0.5)O7:1.0%Eu2+ phosphor shows promise for application in the field of fingerprint identification based on the experimental results. © 2023 by the authors.

Keyword:

Emission spectroscopy Energy conservation Germanium compounds High temperature applications Luminescence of inorganic solids Phosphors Rare earths Silicon compounds Solid state reactions Spectroscopic analysis Temperature X ray diffraction

Community:

  • [ 1 ] [Kong, Xiangqian]College of Chemistry and Materials Science, Fujian Normal University, Fuzhou; 350116, China
  • [ 2 ] [Kong, Xiangqian]Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou; 350116, China
  • [ 3 ] [Kong, Xiangqian]Fujian Key Laboratory of Fuel and Materials in Clean Nuclear Energy System, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
  • [ 4 ] [Qiu, Zhihua]Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou; 350116, China
  • [ 5 ] [Qiu, Zhihua]Fujian Key Laboratory of Fuel and Materials in Clean Nuclear Energy System, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
  • [ 6 ] [Wu, Lina]Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou; 350116, China
  • [ 7 ] [Wu, Lina]Fujian Key Laboratory of Fuel and Materials in Clean Nuclear Energy System, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
  • [ 8 ] [Wu, Lina]College of Chemistry, Fuzhou University, Fuzhou; 350116, China
  • [ 9 ] [Lei, Yunfei]College of Chemistry and Materials Science, Fujian Normal University, Fuzhou; 350116, China
  • [ 10 ] [Chi, Lisheng]Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou; 350116, China
  • [ 11 ] [Chi, Lisheng]Fujian Key Laboratory of Fuel and Materials in Clean Nuclear Energy System, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China

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Source :

Materials

Year: 2023

Issue: 10

Volume: 16

3 . 1

JCR@2023

3 . 1 0 0

JCR@2023

ESI HC Threshold:49

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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