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author:

Zhou, Jiangcong (Zhou, Jiangcong.) [1] | Chen, Mengting (Chen, Mengting.) [2] | Li, Baojuan (Li, Baojuan.) [3] | Lin, Long (Lin, Long.) [4] | Wang, Bo (Wang, Bo.) [5] | Wu, Dewu (Wu, Dewu.) [6] | Ding, Jianyan (Ding, Jianyan.) [7] | Wu, Quansheng (Wu, Quansheng.) [8]

Indexed by:

EI SCIE

Abstract:

Whitlockite beta-Ca-3(PO4)(2)-type materials have multiple crystallographic sites for occupying by rare earth ions to achieve a strong and broadband emitting covering the spectra from cyan to deep red and various abundant heterogeneous substitution ability to develop new luminescent materials. In this work, a broadband emitting Sr8MgGa(PO4)(7):Eu2+ (SMGP) phosphor, deriving from beta-Ca-3(PO4)(2) host by cations substitution, was prepared by solid state reaction at high temperature. Based on the Rietveld refinement results, SMGP host possesses a monoclinic system with a space group C2/m. The optimized doping concentration was determined to be 0.04. The SMGP: 0.04Eu(2+) sample exhibit strong absorption at the wavelength of 250-500 nm, and a broadband emission from 450 to 800 nm covering the spectra from cyan to deep red. However, the SMGP: 0.04Eu(2+) phosphors exhibit poor thermal stability with activation energy as 0.156 eV. By adjusting the composition of the trivalent ions Ga3+/Lu3+, controllable emission color from green to yellow can be achieved in the Sr8MgGa1-xLux(PO4)(7):Eu2+ solid solution phosphors. Finally, a white light-emitting diodes (LED) lamp was prepared by coating the mixtures of SMGP: 0.04Eu(2+) phosphors and BaMgAl10O17:Eu2+ phosphors on the surface of 400 nm near-ultraviolet chip. The optimized white LED lamp exhibits a correlated color temperature of 2991 K and a good color rendering index of 90.2. These results demonstrate the commercialized prospect of SMGP: Eu2+ materials as a broadband emitting phosphor for application in solid state lighting.

Keyword:

Broadband emitting phosphors -Ca-3(PO4)(2)-type materials Eu2+ Excellent color rendering index Multi-luminescent centers Sr8MgGa(PO4)7 White light-emitting diodes Whitlockite &#946

Community:

  • [ 1 ] [Zhou, Jiangcong]Longyan Univ, Coll Chem & Mat Sci, Longyan 364000, Fujian, Peoples R China
  • [ 2 ] [Chen, Mengting]Longyan Univ, Coll Chem & Mat Sci, Longyan 364000, Fujian, Peoples R China
  • [ 3 ] [Li, Baojuan]Longyan Univ, Coll Chem & Mat Sci, Longyan 364000, Fujian, Peoples R China
  • [ 4 ] [Lin, Long]Longyan Univ, Coll Chem & Mat Sci, Longyan 364000, Fujian, Peoples R China
  • [ 5 ] [Wu, Dewu]Longyan Univ, Coll Chem & Mat Sci, Longyan 364000, Fujian, Peoples R China
  • [ 6 ] [Ding, Jianyan]Longyan Univ, Coll Chem & Mat Sci, Longyan 364000, Fujian, Peoples R China
  • [ 7 ] [Wu, Quansheng]Longyan Univ, Coll Chem & Mat Sci, Longyan 364000, Fujian, Peoples R China
  • [ 8 ] [Zhou, Jiangcong]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 9 ] [Chen, Mengting]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 10 ] [Wu, Quansheng]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 11 ] [Wang, Bo]Wuyi Univ, Sch Appl Phys & Mat, Wuyishan 529020, Guangdong, Peoples R China

Reprint 's Address:

  • 周江聪

    [Zhou, Jiangcong]Longyan Univ, Coll Chem & Mat Sci, Longyan 364000, Fujian, Peoples R China;;[Wu, Quansheng]Longyan Univ, Coll Chem & Mat Sci, Longyan 364000, Fujian, Peoples R China;;[Zhou, Jiangcong]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China;;[Wu, Quansheng]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China;;[Wang, Bo]Wuyi Univ, Sch Appl Phys & Mat, Wuyishan 529020, Guangdong, Peoples R China

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Source :

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING

ISSN: 0947-8396

Year: 2021

Issue: 5

Volume: 127

2 . 9 8 3

JCR@2021

2 . 5 0 0

JCR@2023

ESI Discipline: PHYSICS;

ESI HC Threshold:87

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 5

SCOPUS Cited Count: 6

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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