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[期刊论文]

Carbene polymerization from the catalyzed decomposition of diazo compounds: Mechanism and modern development

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author:

Li, F. (Li, F..) [1] | Xiao, L. (Xiao, L..) [2] | Li, B. (Li, B..) [3] | Unfold

Indexed by:

Scopus

Abstract:

Carbene polymerization from the catalyzed decomposition of diazo compounds is a unique non-petroleum-based C1 polymerization pathway toward high-density functional polyolefins. The last 20 years have seen vigorous development in carbene polymerization, such as various efficient initiating systems, high molecular weight and stereoregular polycarbene, controlled carbene polymerization, and the combined copolymerization approaches with other polymerization methodologies. This review highlights the recent advancements in developing the new/old disciplines of carbene polymerization, i.e., carbene insertion polymerization and carbene radical polymerization. The representative copolymerization methodologies, aggregation structures, properties, and applications of polycarbene are also summarized. Finally, the future trends in expanding carbene polymerization potentials are discussed. © 2022 Elsevier B.V.

Keyword:

Carbene insertion polymerization Carbene polymerization Carbene radical polymerization Diazo compounds Functional polyolefins

Community:

  • [ 1 ] [Li, F.]School of Materials Science and Engineering, Hubei Key Laboratory of Plasma Chemistry and Advanced Materials, Wuhan Institute of Technology, Wuhan, 430205, China
  • [ 2 ] [Xiao, L.]College of Chemistry Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 3 ] [Li, B.]School of Materials Science and Engineering, Hubei Key Laboratory of Plasma Chemistry and Advanced Materials, Wuhan Institute of Technology, Wuhan, 430205, China
  • [ 4 ] [Hu, X.]School of Materials Science and Engineering, Hubei Key Laboratory of Plasma Chemistry and Advanced Materials, Wuhan Institute of Technology, Wuhan, 430205, China
  • [ 5 ] [Liu, L.]College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, 430072, China

Reprint 's Address:

  • [Li, F.]School of Materials Science and Engineering, China

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Source :

Coordination Chemistry Reviews

ISSN: 0010-8545

Year: 2022

Volume: 473

2 0 . 6

JCR@2022

2 0 . 3 0 0

JCR@2023

ESI HC Threshold:74

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

30 Days PV: 0

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