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Abstract:
Herein, we report a new method of synthesizing of 2-aminobenzofuran 3-enes via the formal C-S insertion reaction of alkyne-tethered diazo compounds. Metal carbene, as a kind of active synthetic intermediate, plays a very important role in organic synthesis. Through the carbene/alkyne metathesis strategy, a new donor carbene is produced in situ as a key intermediate, which has different reactions from the donor receptor carbene.
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ORGANIC LETTERS
ISSN: 1523-7060
Year: 2023
Issue: 12
Volume: 25
Page: 2113-2117
4 . 9
JCR@2023
4 . 9 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:39
JCR Journal Grade:1
CAS Journal Grade:1
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