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author:

Li, Feifei (Li, Feifei.) [1] | Xiao, Longqiang (Xiao, Longqiang.) [2] (Scholars:肖龙强) | Li, Bang (Li, Bang.) [3] | Hu, Xingyi (Hu, Xingyi.) [4] | Liu, Lijian (Liu, Lijian.) [5]

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Scopus SCIE

Abstract:

Carbene polymerization from the catalyzed decomposition of diazo compounds is a unique nonpetroleum-based C1 polymerization pathway toward high-density functional polyolefins. The last 20 years have seen vigorous development in carbene polymerization, such as various efficient initiating systems, high molecular weight and stereoregular polycarbene, controlled carbene polymerization, and the combined copolymerization approaches with other polymerization methodologies. This review highlights the recent advancements in developing the new/old disciplines of carbene polymerization, i.e., carbene insertion polymerization and carbene radical polymerization. The representative copolymerization methodologies, aggregation structures, properties, and applications of polycarbene are also summarized. Finally, the future trends in expanding carbene polymerization potentials are discussed.(c) 2022 Elsevier B.V. All rights reserved.

Keyword:

Carbene insertion polymerization Carbene polymerization Carbene radical polymerization Diazo compounds Functional polyolefins

Community:

  • [ 1 ] [Li, Feifei]Wuhan Inst Technol, Sch Mat Sci & Engn, Hubei Key Lab Plasma Chem & Adv Mat, Wuhan 430205, Peoples R China
  • [ 2 ] [Li, Bang]Wuhan Inst Technol, Sch Mat Sci & Engn, Hubei Key Lab Plasma Chem & Adv Mat, Wuhan 430205, Peoples R China
  • [ 3 ] [Hu, Xingyi]Wuhan Inst Technol, Sch Mat Sci & Engn, Hubei Key Lab Plasma Chem & Adv Mat, Wuhan 430205, Peoples R China
  • [ 4 ] [Xiao, Longqiang]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Liu, Lijian]Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China

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Source :

COORDINATION CHEMISTRY REVIEWS

ISSN: 0010-8545

Year: 2022

Volume: 473

2 0 . 6

JCR@2022

2 0 . 3 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:74

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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