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Carbene polymerization from the catalyzed decomposition of diazo compounds is a unique nonpetroleum-based C1 polymerization pathway toward high-density functional polyolefins. The last 20 years have seen vigorous development in carbene polymerization, such as various efficient initiating systems, high molecular weight and stereoregular polycarbene, controlled carbene polymerization, and the combined copolymerization approaches with other polymerization methodologies. This review highlights the recent advancements in developing the new/old disciplines of carbene polymerization, i.e., carbene insertion polymerization and carbene radical polymerization. The representative copolymerization methodologies, aggregation structures, properties, and applications of polycarbene are also summarized. Finally, the future trends in expanding carbene polymerization potentials are discussed.(c) 2022 Elsevier B.V. All rights reserved.
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COORDINATION CHEMISTRY REVIEWS
ISSN: 0010-8545
Year: 2022
Volume: 473
2 0 . 6
JCR@2022
2 0 . 3 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:74
JCR Journal Grade:1
CAS Journal Grade:1
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0
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