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Abstract：
Transition-metal-catalyzed direct inert C-H bond functionalization has attracted much attention over the past decades. However, because of the high strain energy of the suspected palladacycle generated via C-H bond palladation, direct functionalization of a C-H bond less than a three-bond distance from a catalyst center is highly challenging. In this short review, we summarize the advances on palladium-catalyzed bridging C-H activation, in which an inert proximal C-H bond palladation is promoted by the elementary step of migratory insertion of an alkene, an alkyne or a metal carbene intermediate. 1 Introduction 2 Palladium-Catalyzed Alkene Bridging C-H Activation 2.1 Intramolecular Reactions 2.2 Intermolecular Reactions 3 Palladium-Catalyzed Alkyne Bridging C-H Activation 3.1 Intermolecular Reactions 3.2 Intramolecular Reactions 4 Palladium-Catalyzed Carbene Bridging C-H Activation 5 Conclusion and Outlook
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SYNTHESIS-STUTTGART
ISSN： 0039-7881
Year： 2020
3 . 1 5 7
JCR@2020
2 . 2 0 0
JCR@2023
ESI Discipline： CHEMISTRY;
ESI HC Threshold：160
JCR Journal Grade：2
CAS Journal Grade：3
Cited Count：
WoS CC Cited Count： 0
SCOPUS Cited Count：
ESI Highly Cited Papers on the List： 0 Unfold All
WanFang Cited Count：
Chinese Cited Count：
30 Days PV： 1
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