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Abstract:
Inkjet printing technique is susceptible to form coffer-ring patterns and inhomogeneous films owing to the evaporation and its accompanying hydrodynamics of microscale quantum dot droplet. Pioneer efforts are usually confined to two-dimensional flat substrates and inks with mixed solvents/additives. Herein we demonstrate that physically confined space offers an additional parameter in tailoring such processes of droplets and the following quantum-dot self-assembly deposition, without extra modification of quantum dots or solvent chemistry. Owing to the boundary of physically confined space, two three-phase border lines in both the bottom center (horizontal direction) and the barrier of the bank substrate (vertical direction) arise, inducing dual capillary flows and Marangoni backflows. The evaporation, fluid flow, and film-forming process in physically confined space are studied by introducing well-prepared single-solvent quantum dots inks. The systematical analysis offers valuable instructions including ink preparation, surface modification, and postprocessing evaporation technique for inkjet-printed patterning applications, especially for pixelated display, polychrome patterning, and sensor array.
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JOURNAL OF PHYSICAL CHEMISTRY LETTERS
ISSN: 1948-7185
Year: 2021
Issue: 35
Volume: 12
Page: 8605-8613
6 . 8 8 8
JCR@2021
4 . 9 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:117
JCR Journal Grade:1
CAS Journal Grade:1
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0
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