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author:

Chen, Zhi-Jie (Chen, Zhi-Jie.) [1] | Zhu, Jun-Qiu (Zhu, Jun-Qiu.) [2] | Shao, Yan-Qun (Shao, Yan-Qun.) [3] (Scholars:邵艳群) | Yi, Zhao-Yu (Yi, Zhao-Yu.) [4] | Tang, Dian (Tang, Dian.) [5] (Scholars:唐电)

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Abstract:

RuO2-TiO2 coating were prepared by thermal decomposition method on pure titanium TA2 substrate at 270. The supercapacitor behavior of RuO2-TiO2 coating was investigated by cyclic voltammetry(CV), electrochemical impedance spectroscopy (EIS) and charging-discharging test in 0.5 mol/L H2SO4, 0.5 mol/L Na2SO4 and 1.0 mol/L NaOH electrolytes, respectively. The results show that the Ti/RuO2-TiO2 electrode has low charge transfer resistance in acidic and alkaline electrolytes, and the specific capacitance of 550 F/g and 578 F/g are obtained in these two electrolytes, respectively. Conversely, the electrode has relative higher charge transfer resistance and lower specific capacitance (335 F/g) in neutral Na2SO4 electrolyte than that of in acidic and alkaline electrolytes. However, the electrode losing 17% and 29% of the maximum capacity after 2000 charging-discharging cycles in acidic and alkaline electrolytes, respectively, but just only 3% lost in neutral Na2SO4 solution. Combined with the SEM and EDS analysis, the electrode is hardly corroded in Na2SO4 solution, thus exhibits good cycle stability. In contrast, Ti/RuO2-TiO2 electrodes occur serious surface corrosion in NaOH solution, while occurring serious pitting corrosion in H2SO4 solution. Severe corrosion results in a significantly reduction of active substance, and thus reduces the charge capacity of the electrode. © 2016, Science Press. All right reserved.

Keyword:

Capacitance Charge transfer Coatings Cyclic voltammetry Decomposition Electrochemical corrosion Electrochemical impedance spectroscopy Electrodes Electrolytes Electrolytic capacitors Pitting Ruthenium compounds Sodium hydroxide Sodium sulfate Supercapacitor Titanium dioxide

Community:

  • [ 1 ] [Chen, Zhi-Jie]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 2 ] [Zhu, Jun-Qiu]College of Materials Science and Engineering, Xiamen University of Technology, Xiamen; 361024, China
  • [ 3 ] [Shao, Yan-Qun]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 4 ] [Yi, Zhao-Yu]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 5 ] [Tang, Dian]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China

Reprint 's Address:

  • 邵艳群

    [shao, yan-qun]college of materials science and engineering, fuzhou university, fuzhou; 350108, china

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Source :

Chinese Journal of Nonferrous Metals

ISSN: 1004-0609

CN: 43-1238/TG

Year: 2016

Issue: 12

Volume: 26

Page: 2580-2588

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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