The　copper(I)　complex　with　N-(2-carboxyphenyl)　salicylidenamine　and　imidazole　ligands,　Cu(C14H9NO3)　(C3H4N2),　was　synthesized.　The　crystal　belongs　to　orthorhombic,　space　group　Pca2(1),　with　the　crystal　cell　parameters:　a=0.944　53(12)　nm,　b=1.122　78(9)　nm,　c=2.912　3(4)　nm,　V=3.　088　5(6)　nm(3),　M-r,370.　84,　Z=8,　R=0.036,　wR=0.087,　GOF=0.975.　The　copper(　I)　ion　lies　in　a　distorted　square-planar　environment　composed　of　two　oxygen　atoms,　one　nitrogen　atom　of　the　tridentate　Schiff　base　ligand　and　one　nitrogen　atom　of　the　imidazole　ligand.　The　complex　was　also　characterized　by　elementary　analysis,　IRI　UV-Vis,　TG　and　cycle　voltammetry　measurement.