Synthesis, Crystal Structure and Characterization of Complex Cu(C14H9NO3)(C3H4N 2) - Details

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Abstract：

The　copper　(II)　complex　with　N-(2-carboxyphenyl)salicylidenamine　and　imidazole　ligands,　Cu(C14H9NO3)(C3H4N　2),　was　synthesized.　The　crystal　belongs　to　orthorhombic,　space　group　Pca21,　with　the　crystal　cell　parameters-　a=0.　944　53(12)　nm,　6=1.　122　78(9)　nm,　c=2.　912　3(4)　nm,　V=　3.　088　5(6)　nm3,　Mr=370.　84,　Z=8,　R=0.　036,　wR=0.　087,　GOF　=　0.　975.　The　copper(II)　ion　lies　in　a　distorted　square-planar　environment　composed　of　two　oxygen　atoms,　one　nitrogen　atom　of　the　tridentate　Schiff　base　ligand　and　one　nitrogen　atom　of　the　imidazole　ligand.　The　complex　was　also　characterized　by　elementary　analysis,　IR,　UV-Vis,　TG　and　cycle　voltammetry　measurement.

Keyword：

Copper(II) complex; Crystal structure; Imidazole; Schiff base

Community：

[ 1 ] [Gao, S.]Department of Chemistry, Key Lab. Inorg. Synthesis P., Jilin University, Changchun 130023, China
[ 2 ] [Shi, Z.]Department of Chemistry, Key Lab. Inorg. Synthesis P., Jilin University, Changchun 130023, China
[ 3 ] [Hua, J.]Department of Chemistry, Key Lab. Inorg. Synthesis P., Jilin University, Changchun 130023, China
[ 4 ] [Feng, S.-H.]Department of Chemistry, Key Lab. Inorg. Synthesis P., Jilin University, Changchun 130023, China
[ 5 ] [Xu, R.-R.]Department of Chemistry, Key Lab. Inorg. Synthesis P., Jilin University, Changchun 130023, China
[ 6 ] [Liu, S.-X.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China
[ 7 ] [Huo, L.-H.]Department of Chemistry, Heilong Jiang University, Harbin 150080, China
[ 8 ] [Chen, P.-G.]Department of Chemistry, Heilong Jiang University, Harbin 150080, China

Reprint 's Address：

[Gao, S.]Department of Chemistry, Key Lab. Inorg. Synthesis P., Jilin University, Changchun 130023, China

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Source ：

Chemical Journal of Chinese Universities

ISSN： 0251-0790

Year： 2000

Issue： 2

Volume： 21

Page： 180-

0 . 5 9

JCR@2000

0 . 7 0 0

JCR@2023

JCR Journal Grade：3

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 2

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