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Abstract:
Six palladium (11) complexes with isonitrosoethylacetoacetate imine Schiff base ligands, Pd (R-IEAI)(2), were prepared and characterized by IR, Raman and electronic spectra. Complex tran Pd(p-CH3C6H4-IEAI)(2) (2) crystallizes in the monoclinic system, space group P2(1), / c, with a = 1.2002 (2), b = 0.9972 (2), c = 1.1121 (2) rim, beta = 90.43 (3)degrees, Z = 2, F (000) = 616, A = 7.44cm(-1). The final R and wR are 0.0244 and 0.0625 for 2620 observed reflections with I greater than or equal to 2sigma(I), respectively. The geometry around the Pd (11) ions in those complexes has a distorted PdN4 square plane, the Schiff base ligands R-IEAI(-) being coordinated through their oximino-nitrogen atoms and imino-nitrogen atoms.
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CHINESE JOURNAL OF INORGANIC CHEMISTRY
ISSN: 1001-4861
CN: 32-1185/O6
Year: 2002
Issue: 9
Volume: 18
Page: 929-932
0 . 4 9 4
JCR@2002
0 . 8 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:4
Cited Count:
WoS CC Cited Count: 2
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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