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Abstract:
The complex containing ferroceneyl, Cd(dppf) I-2(dppf = 1, 1-bis(diphenylphosphino) ferrocene), was synthesized and characterized by 111, Uv-vis DRIS spectrum and X-ray diffraction. The crystal belongs to monoclinic, space group C2/c, a = 37.439(3) Angstrom, b = 10.2472(6) Angstrom, c = 18.719(1) Angstrom, beta = 110.4715(16)degrees, V = 6727.8 (8) Angstrom(3), Z = 8, D-e = 1.818g . cm(-3), F(000) = 3536, mu = 3.015mm(-1), R = 0.0308, wR = 0.0692. dppf coordinates to Cd (II) as bidentate ligand, and the coordination environment of Cd (II) is a distorted tetrahedron. The electronic structures of Cd(dppf)I-2 and Cd(dppf)Br-2 are discussed by quantum chemistry calculation.
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CHINESE JOURNAL OF INORGANIC CHEMISTRY
ISSN: 1001-4861
CN: 32-1185/O6
Year: 2002
Issue: 11
Volume: 18
Page: 1119-1122
0 . 4 9 4
JCR@2002
0 . 8 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:4
Cited Count:
WoS CC Cited Count: 2
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
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