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author:

Huang, ZX (Huang, ZX.) [1] | Wang, XL (Wang, XL.) [2] | Liu, SX (Liu, SX.) [3]

Indexed by:

Scopus SCIE CSCD

Abstract:

The complex containing ferroceneyl, Cd(dppf) I-2(dppf = 1, 1-bis(diphenylphosphino) ferrocene), was synthesized and characterized by 111, Uv-vis DRIS spectrum and X-ray diffraction. The crystal belongs to monoclinic, space group C2/c, a = 37.439(3) Angstrom, b = 10.2472(6) Angstrom, c = 18.719(1) Angstrom, beta = 110.4715(16)degrees, V = 6727.8 (8) Angstrom(3), Z = 8, D-e = 1.818g . cm(-3), F(000) = 3536, mu = 3.015mm(-1), R = 0.0308, wR = 0.0692. dppf coordinates to Cd (II) as bidentate ligand, and the coordination environment of Cd (II) is a distorted tetrahedron. The electronic structures of Cd(dppf)I-2 and Cd(dppf)Br-2 are discussed by quantum chemistry calculation.

Keyword:

Cd(II) complex crystal structure electronic structure ferrocene synthesis

Community:

  • [ 1 ] Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 黄尊行

    [Huang, ZX]Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China

Email:

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Source :

CHINESE JOURNAL OF INORGANIC CHEMISTRY

ISSN: 1001-4861

CN: 32-1185/O6

Year: 2002

Issue: 11

Volume: 18

Page: 1119-1122

0 . 4 9 4

JCR@2002

0 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

Cited Count:

WoS CC Cited Count: 2

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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