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author:

Huang, ZX (Huang, ZX.) [1] | Wang, XL (Wang, XL.) [2] | Liu, SX (Liu, SX.) [3]

Indexed by:

Scopus SCIE CSCD

Abstract:

A binuclear complex including, ferrocenyl, Cu-2{Fe(C5H5)[C5H4CH2N(CH3)(2)]}(2) (CH3COO)(4), was synthesized and characterized by X-ray diffraction. The title complex crystallizes in triclinic, space group PT with a = 8.2779(8), b = 9.4830(8), c = 12.262(1) Angstrom, alpha = 81.079(5), beta = 80.620(4), gamma = 78.960(4)degrees, V = 924.4(1) Angstrom(3), Z = 1, C34H46Cu2Fe2N2O8, M-r = 849.51, D-c= 1.526 g/cm(3), lambda(MoKalpha) = 0.71073 Angstrom, mu = 1.954 mm(-1), F(000) = 438, R = 0.0297 and wR = 0.0901. Both cyclopentadienyl rings in each dmaf (dmaf = (dimethylaminomethyl)ferrocene, Fe(C5H5)[C5H4CH2N(CH3)(2)]) have an eclipsed conformation. The binuclear molecule has a crystallographic centrosymmetry; four acetates and two Cu atoms form a cage structure with the distance between two neighboring Cu atoms of 2.655(1) Angstrom.

Keyword:

binuclear complex copper complex crystal structure (dimethylaminomethyl)-ferrocene

Community:

  • [ 1 ] Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 黄尊行

    [Huang, ZX]Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China

Email:

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Source :

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY

ISSN: 0254-5861

CN: 35-1112/TQ

Year: 2002

Issue: 5

Volume: 21

Page: 505-508

0 . 3 2 4

JCR@2002

5 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

Cited Count:

WoS CC Cited Count: 3

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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