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Abstract:
A binuclear complex including, ferrocenyl, Cu-2{Fe(C5H5)[C5H4CH2N(CH3)(2)]}(2) (CH3COO)(4), was synthesized and characterized by X-ray diffraction. The title complex crystallizes in triclinic, space group PT with a = 8.2779(8), b = 9.4830(8), c = 12.262(1) Angstrom, alpha = 81.079(5), beta = 80.620(4), gamma = 78.960(4)degrees, V = 924.4(1) Angstrom(3), Z = 1, C34H46Cu2Fe2N2O8, M-r = 849.51, D-c= 1.526 g/cm(3), lambda(MoKalpha) = 0.71073 Angstrom, mu = 1.954 mm(-1), F(000) = 438, R = 0.0297 and wR = 0.0901. Both cyclopentadienyl rings in each dmaf (dmaf = (dimethylaminomethyl)ferrocene, Fe(C5H5)[C5H4CH2N(CH3)(2)]) have an eclipsed conformation. The binuclear molecule has a crystallographic centrosymmetry; four acetates and two Cu atoms form a cage structure with the distance between two neighboring Cu atoms of 2.655(1) Angstrom.
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CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
ISSN: 0254-5861
CN: 35-1112/TQ
Year: 2002
Issue: 5
Volume: 21
Page: 505-508
0 . 3 2 4
JCR@2002
5 . 9 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:4
Cited Count:
WoS CC Cited Count: 3
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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