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author:

Wang, XL (Wang, XL.) [1] | Huang, ZX (Huang, ZX.) [2] | Liu, SX (Liu, SX.) [3]

Indexed by:

Scopus SCIE PKU CSCD

Abstract:

The title complex Cd(dppf)Br-2 (dppf=1,1'-bis(diphenylphosphino)ferrocene) (C34H28Br2 P2CdFe, M-r = 826.57) has been synthesized and characterized by X-ray diffraction. The crystal is in monoclinic, space group C2/c with cell parameters: a = 34.285(4), b = 10.050(1), c = 18.697(2)Angstrom, beta = 98.843(3)degrees, V = 6366(1)Angstrom (3), Z = 8, D-c = 1.725g/cm(3), lambda (MoK alpha) = 0.71073 Angstrom, mu = 3.757 mm(-1), F(000) = 3248. The final refinement with 4469 observed reflections and 361 parameters gave R = 0.0584 and wR = 0.1522. The 1,1'-bis(diphenylphosphino)ferrocene group is connected to the Cd atom as a bidentate ligand. The Cd atom has a distorted tetrahedral coordination.

Keyword:

1,1 '-bis(diphenylphosphino)ferrocene cadmium complex crystal structure synthesis

Community:

  • [ 1 ] Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 黄尊行

    [Huang, ZX]Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China

Email:

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Source :

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY

ISSN: 0254-5861

CN: 35-1112/TQ

Year: 2001

Issue: 6

Volume: 20

Page: 486-488

0 . 1 8 4

JCR@2001

5 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

Cited Count:

WoS CC Cited Count: 7

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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