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Abstract：
The complex containing ferroceneyl, Cd(dppf) I2(dppf=1, 1-bis(diphenylphosphino) ferrocene), was synthesized and characterized by IR, Uv-vis DRIS spectrum and X-ray diffraction. The crystal belongs to monoclinic, space group C2/ c, a = 37. 439(3) Å, b = 10. 2472(6) Å, c = 18. 719(1) Å, β = 110.4715(16)°, V = 6727.8 (8) Å3, Z = 8, Dc = 1.818g · cm-3, F(000) = 3536, μ = 3.015mm-1, R = 0.0308, wR = 0.0692. dppf coordinates to Cd (II) as bidentate ligand, and the coordination environment of Cd (II) is a distorted tetrahedron. The electronic structures of Cd(dppf)I2 and Cd(dppf)Br2 are discussed by quantum chemistry calculation.
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Chinese Journal of Inorganic Chemistry
ISSN： 1001-4861
Year： 2002
Issue： 11
Volume： 18
Page： 1119-1122
0 . 4 9 4
JCR@2002
0 . 8 0 0
JCR@2023
JCR Journal Grade：4
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ESI Highly Cited Papers on the List： 0 Unfold All
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