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Abstract:
The organic-inorganic hybrid [(C14H18N 2)(Pb2I6)]n ([C14H 18N2]2+ = N,N′-1,4-buthylenedipyridinium (BDP)) with one-dimensional structure was self-assembling synthesized by the organic quaternary ammonium template. It crystallizes in monoclinic, space group P21/n with a = 8.2596(9), b = 15.1363(19), c = 11.1603(13) Å, β = 97.915(5)°, C14H18N2Pb 2I6, Mr = 1390.10, V = 1382.0(3) Å3, Z = 2, Dc = 3.341 g/cm3, μ(MoKα) = 18.870 mm-1, F(000) = 1196, the final R = 0.0420 and wR = 0.0921 for 2156 observed reflections with I > 2σ(I). The title compound consists of cations ([C14H18N2] 2+) and anion chain ([Pb2I62-] n) which are combined by static attractive forces in the crystal.
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CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
ISSN: 0254-5861
CN: 35-1112/TQ
Year: 2004
Issue: 9
Volume: 23
Page: 1013-1016
0 . 7 3 4
JCR@2004
5 . 9 0 0
JCR@2023
JCR Journal Grade:3
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