Two　new　organically　templated　lead(II)　iodide　complexes,　[(nbq)(PbI3)](n)　1　and　{[(CH3)(3)NC2H4N(CH3)(3)](3)(Pb6I18)}(n)　2,　have　been　synthesized　in　the　presence　of　aromatic　and　aliphatic　quaternary　ammonium　compounds,　N-(n-　butyl)　quinolinium　(nbq(+))　and　[(CH3)(3)NC2H4N(CH3)(3)](2+),　respectively,　acting　as　structure-directing　agents.　Both　1　and　2　consist　of　uncoordinated　structure-directing　agents　and　inorganic　moieties　bound　to　the　organic　structure-directing　agents.　In　1,　an　inorganic　(PbI3-)(n)　one-dimensional　polyanion　chain　is　built　up　by　face-sharing　of　distorted　PbI6　tetrahedra.　The　inorganic　framework　of　2　presents　a　two-dimensional　arrangement　that　could　be　discussed　in　terms　of　[Pb3I10](4-)　building　blocks.　Static　attractive　interactions　between　organic　countercations　and　inorganic　moieties　were　revealed　through　the　crystal　packing.　Density　functional　theory　calculations　indicate　that　1　possesses　semiconductor　properties,　tuned　by　the　pi-electrons　of　nbq(+).　In　contrast,　2　is　conductive　in　the　direction　of　aliphatic　quaternary　ammonium　moiety.