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author:

Zeng, Anran (Zeng, Anran.) [1] | Zheng, Yuying (Zheng, Yuying.) [2] (Scholars:郑玉婴) | Qiu, Shangchang (Qiu, Shangchang.) [3] | Guo, Yong (Guo, Yong.) [4] | Li, Baoming (Li, Baoming.) [5] (Scholars:李宝铭)

Indexed by:

EI Scopus SCIE

Abstract:

It was found that lanthanum complex of cyclodextrin derivative (beta-CD-MAH-La) was a highly active beta-nucleating agent for isotactic polypropylene (iPP) in this study. The influence of the nucleating agent on mechanical properties and isothermal and nonisothermal crystallization behavior of iPP has been investigated. Results showed that beta-CD-MAH-La was efficient in inducing the crystallization of iPP into beta-modification (beta-iPP), with K (beta) value of 0.84, while the content of nucleating agent was 0.8 wt.%. beta-iPP could form extensively in the isothermal crystallization temperature range from 110 A degrees C to 140 A degrees C, and the highest amount of beta-crystal content was formed at 130 A degrees C. Besides, it can be known that the addition of beta-CD-MAH-La can obviously facilitate the overall crystallization process of iPP. Under nonisothermal condition, beta-iPP formed at the suitable cooling rates, ranging from 5 A degrees C to 10 A degrees C/min. Furthermore, the nucleation mechanism of beta-CD-MAH-La for iPP was correlated to the special configuration of beta-CD-MAH-La.

Keyword:

beta-nucleating agent Crystallization behavior Cyclodextrin derivative Isotactic polypropylene

Community:

  • [ 1 ] [Zheng, Yuying]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Li, Baoming]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Zeng, Anran]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Qiu, Shangchang]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Guo, Yong]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • 郑玉婴

    [Zheng, Yuying]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China

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Source :

COLLOID AND POLYMER SCIENCE

ISSN: 0303-402X

Year: 2011

Issue: 10

Volume: 289

Page: 1157-1166

2 . 3 3 1

JCR@2011

2 . 2 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 12

SCOPUS Cited Count: 13

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

Online/Total:126/9984616
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