The　present　work　reported　a　facile　and　simple　in　situ　solvothermal　growth　method　for　immobilization　of　metal-organic　framework　UiO-66　via　covalent　bonding　on　amino　functional　silica　fiber　for　highly　sensitive　solid-phase　microextraction　(SPME)　of　ten　polycyclic　aromatic　hydrocarbons　(PAHs)　by　coupling　with　gas　chromatography-mass　spectrometry　(GC-MS)　analysis.　The　developed　SPME　coated　fiber　has　been　characterized　through　SEM,　TGA　and　XRD,　confirmed　the　coating　thickness　of　similar　to　25　mu　m　with　high　thermal　and　chemical　stability.　Under　optimized　conditions,　the　obtained　method　exhibited　satisfactory　linearity　in　range　of　1.0-5000.0　ng　L-1　for　all　the　PAHs.　The　low　detection　limits　were　from　0.28　ng　L-1　to　0.60　ng　L-1　(S/N　=3).　The　UiO-66　coated　fibers　showed　good　repeatability　(RSDs　less　than　8.2%,　n=5)　and　satisfying　reproducibility　between　fiber　to　fiber　(RSDs　less　than　8.9%,　n　=　5).　This　method　was　successfully　used　for　simultaneous　determination　of　ten　PAHs　from　Minjiang　water　and　soil　samples　with　satisfactory　recoveries　of　87.0-113.6%　and　83.8-116.7%,　respectively.　Experimental　results　shows　that　the　chemical　bonding　approach　has　dramatically　improve　the　stability　and　lifetime　of　pure　MOFs　coating　for　SPME　in　sample　pretreatment.　(C)　2016　Elsevier　B.V.　All　rights　reserved.