The　present　work　reported　a　facile　and　simple　in　situ　solvothermal　growth　method　for　immobilization　of　metal-organic　framework　UiO-66　via　covalent　bonding　on　amino　functional　silica　fiber　for　highly　sensitive　solid-phase　microextraction　(SPME)　of　ten　polycyclic　aromatic　hydrocarbons　(PAHs)　by　coupling　with　gas　chromatography-mass　spectrometry　(GC-MS)　analysis.　The　developed　SPME　coated　fiber　has　been　characterized　through　SEM,　TGA　and　XRD,　confirmed　the　coating　thickness　of　~25　μm　with　high　thermal　and　chemical　stability.　Under　optimized　conditions,　the　obtained　method　exhibited　satisfactory　linearity　in　range　of　1.0-5000.0　ng　L-1　for　all　the　PAHs.　The　low　detection　limits　were　from　0.28　ng　L-1　to　0.60　ng　L-1　(S/N　=　3).　The　UiO-66　coated　fibers　showed　good　repeatability　(RSDs　less　than　8.2%,　n　=　5)　and　satisfying　reproducibility　between　fiber　to　fiber　(RSDs　less　than　8.9%,　n　=　5).　This　method　was　successfully　used　for　simultaneous　determination　of　ten　PAHs　from　Minjiang　water　and　soil　samples　with　satisfactory　recoveries　of　87.0-113.6%　and　83.8-116.7%,　respectively.　Experimental　results　shows　that　the　chemical　bonding　approach　has　dramatically　improve　the　stability　and　lifetime　of　pure　MOFs　coating　for　SPME　in　sample　pretreatment.　©　2016　Elsevier　B.V..