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A new rare-earth borate Er6B4O15 was synthesized by a solid-state reaction technique. The crystal was obtained by a flux method. Single-crystal X-ray diffraction analysis revealed that the crystal structure is composed of ErO6 polyhedra sharing edges and BO3 groups. The absorption, near-infrared fluorescence spectra and the fluorescence decay curve of Er: I-4(13/2) energy level in the Er6B4O15 crystal were measured at room temperature. The absorption peak was located at 977 nm with absorption cross section of 1.16 x 10(-21) cm(2) and a full width at half-maximum (FWHM) of 16 nm, which is very suitable for commercial 980 nm laser diode pumping. A maximum emission peak at 1560 mm with a broad FWHM of 64 nm was observed in this crystal because of the Er3+ transition I-4(13/2)-> I-4(15/2), while the emission cross section was calculated to be 8.53 x 10(-20) cm(2). These results imply that the Er6B4O15 crystal is a promising candidate material for the achievement of an eye-safe near-infrared wavelength laser.
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ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS
ISSN: 2052-5206
Year: 2018
Volume: 74
Page: 132-136
6 . 7 3 2
JCR@2018
1 . 3 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:209
JCR Journal Grade:1
CAS Journal Grade:2
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ESI Highly Cited Papers on the List: 0 Unfold All
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Chinese Cited Count:
30 Days PV: 2
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