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author:

Wang, Yan (Wang, Yan.) [1] | Zhang, Wei (Zhang, Wei.) [2] | Li, Ziyi (Li, Ziyi.) [3] | Li, Jianfu (Li, Jianfu.) [4] | Zhu, Zhaojie (Zhu, Zhaojie.) [5] | You, Zhenyu (You, Zhenyu.) [6] | Tu, Chaoyang (Tu, Chaoyang.) [7]

Indexed by:

EI Scopus SCIE

Abstract:

A new rare-earth borate Er6B4O15 was synthesized by a solid-state reaction technique. The crystal was obtained by a flux method. Single-crystal X-ray diffraction analysis revealed that the crystal structure is composed of ErO6 polyhedra sharing edges and BO3 groups. The absorption, near-infrared fluorescence spectra and the fluorescence decay curve of Er: I-4(13/2) energy level in the Er6B4O15 crystal were measured at room temperature. The absorption peak was located at 977 nm with absorption cross section of 1.16 x 10(-21) cm(2) and a full width at half-maximum (FWHM) of 16 nm, which is very suitable for commercial 980 nm laser diode pumping. A maximum emission peak at 1560 mm with a broad FWHM of 64 nm was observed in this crystal because of the Er3+ transition I-4(13/2)-> I-4(15/2), while the emission cross section was calculated to be 8.53 x 10(-20) cm(2). These results imply that the Er6B4O15 crystal is a promising candidate material for the achievement of an eye-safe near-infrared wavelength laser.

Keyword:

crystal growth crystal structure Er6B4O15 flux method optical properties

Community:

  • [ 1 ] [Wang, Yan]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Yangqiao West Rd 155, Fuzhou 3500021, Fujian, Peoples R China
  • [ 2 ] [Zhang, Wei]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Yangqiao West Rd 155, Fuzhou 3500021, Fujian, Peoples R China
  • [ 3 ] [Li, Jianfu]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Yangqiao West Rd 155, Fuzhou 3500021, Fujian, Peoples R China
  • [ 4 ] [Zhu, Zhaojie]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Yangqiao West Rd 155, Fuzhou 3500021, Fujian, Peoples R China
  • [ 5 ] [You, Zhenyu]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Yangqiao West Rd 155, Fuzhou 3500021, Fujian, Peoples R China
  • [ 6 ] [Tu, Chaoyang]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Yangqiao West Rd 155, Fuzhou 3500021, Fujian, Peoples R China
  • [ 7 ] [Zhang, Wei]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China
  • [ 8 ] [Li, Ziyi]Sichuan Univ, Coll Chem Engn, Chengdu 610227, Sichuan, Peoples R China

Reprint 's Address:

  • [Wang, Yan]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Yangqiao West Rd 155, Fuzhou 3500021, Fujian, Peoples R China;;[Tu, Chaoyang]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Yangqiao West Rd 155, Fuzhou 3500021, Fujian, Peoples R China

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Source :

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS

ISSN: 2052-5206

Year: 2018

Volume: 74

Page: 132-136

6 . 7 3 2

JCR@2018

1 . 3 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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