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author:

Wang, Y. (Wang, Y..) [1] | Zhang, W. (Zhang, W..) [2] | Li, Z. (Li, Z..) [3] | Li, J. (Li, J..) [4] | Zhu, Z. (Zhu, Z..) [5] | You, Z. (You, Z..) [6] | Tu, C. (Tu, C..) [7]

Indexed by:

Scopus

Abstract:

A new rare-earth borate Er6B4O15 was synthesized by a solid-state reaction technique. The crystal was obtained by a flux method. Single-crystal X-ray diffraction analysis revealed that the crystal structure is composed of ErO6 polyhedra sharing edges and BO3 groups. The absorption, near-infrared fluorescence spectra and the fluorescence decay curve of Er: 4I13/2 energy level in the Er6B4O15 crystal were measured at room temperature. The absorption peak was located at 977 nm with absorption cross section of 1.16 × 10−21 cm2 and a full width at half-maximum (FWHM) of 16 nm, which is very suitable for commercial 980 nm laser diode pumping. A maximum emission peak at 1560 mm with a broad FWHM of 64 nm was observed in this crystal because of the Er3+ transition 4I13/2→4I15/2, while the emission cross section was calculated to be 8.53 × 10−20 cm2. These results imply that the Er6B4O15 crystal is a promising candidate material for the achievement of an eye-safe near-infrared wavelength laser. © International Union of Crystallography, 2018

Keyword:

crystal growth; crystal structure; Er6B4O15; flux method; optical properties

Community:

  • [ 1 ] [Wang, Y.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road No. 155, Fuzhou City, Fujian Province 3500021, China
  • [ 2 ] [Zhang, W.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road No. 155, Fuzhou City, Fujian Province 3500021, China
  • [ 3 ] [Zhang, W.]College of Chemistry, Fuzhou University, Fuzhou City, Fujian Province 350116, China
  • [ 4 ] [Li, Z.]College of Chemical Engineering, Sichuan University, Chengdu City, Sichuan Province 610227, China
  • [ 5 ] [Li, J.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road No. 155, Fuzhou City, Fujian Province 3500021, China
  • [ 6 ] [Zhu, Z.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road No. 155, Fuzhou City, Fujian Province 3500021, China
  • [ 7 ] [You, Z.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road No. 155, Fuzhou City, Fujian Province 3500021, China
  • [ 8 ] [Tu, C.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road No. 155, Fuzhou City, Fujian Province 3500021, China

Reprint 's Address:

  • [Wang, Y.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road No. 155, China

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Source :

Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials

ISSN: 2052-5192

Year: 2018

Issue: 2

Volume: 74

Page: 132-136

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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