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author:

Wang, Yan (Wang, Yan.) [1] | Zhang, Wei (Zhang, Wei.) [2] | Li, Ziyi (Li, Ziyi.) [3] | Li, Jianfu (Li, Jianfu.) [4] | Zhu, Zhaojie (Zhu, Zhaojie.) [5] | You, Zhenyu (You, Zhenyu.) [6] | Tu, Chaoyang (Tu, Chaoyang.) [7]

Indexed by:

EI

Abstract:

A new rare-earth borate Er6B4O15 was synthesized by a solid-state reaction technique. The crystal was obtained by a flux method. Single-crystal X-ray diffraction analysis revealed that the crystal structure is composed of ErO6 polyhedra sharing edges and BO3 groups. The absorption, near-infrared fluorescence spectra and the fluorescence decay curve of Er: 4I13/2 energy level in the Er6B4O15 crystal were measured at room temperature. The absorption peak was located at 977 nm with absorption cross section of 1.16 × 10−21 cm2 and a full width at half-maximum (FWHM) of 16 nm, which is very suitable for commercial 980 nm laser diode pumping. A maximum emission peak at 1560 mm with a broad FWHM of 64 nm was observed in this crystal because of the Er3+ transition 4I13/2→4I15/2, while the emission cross section was calculated to be 8.53 × 10−20 cm2. These results imply that the Er6B4O15 crystal is a promising candidate material for the achievement of an eye-safe near-infrared wavelength laser. © International Union of Crystallography, 2018

Keyword:

Chromium compounds Crystal growth Crystallization Crystal structure Erbium compounds Fluorescence Full width at half maximum Infrared devices Optical properties Pumping (laser) Rare earths Single crystals Solid state reactions X ray powder diffraction

Community:

  • [ 1 ] [Wang, Yan]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road No. 155, Fuzhou City; Fujian Province; 3500021, China
  • [ 2 ] [Zhang, Wei]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road No. 155, Fuzhou City; Fujian Province; 3500021, China
  • [ 3 ] [Zhang, Wei]College of Chemistry, Fuzhou University, Fuzhou City; Fujian Province; 350116, China
  • [ 4 ] [Li, Ziyi]College of Chemical Engineering, Sichuan University, Chengdu City; Sichuan Province; 610227, China
  • [ 5 ] [Li, Jianfu]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road No. 155, Fuzhou City; Fujian Province; 3500021, China
  • [ 6 ] [Zhu, Zhaojie]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road No. 155, Fuzhou City; Fujian Province; 3500021, China
  • [ 7 ] [You, Zhenyu]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road No. 155, Fuzhou City; Fujian Province; 3500021, China
  • [ 8 ] [Tu, Chaoyang]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road No. 155, Fuzhou City; Fujian Province; 3500021, China

Reprint 's Address:

  • [wang, yan]key laboratory of optoelectronic materials chemistry and physics, fujian institute of research on the structure of matter, chinese academy of sciences, yangqiao west road no. 155, fuzhou city; fujian province; 3500021, china

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Source :

Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials

ISSN: 2052-5192

Year: 2018

Issue: 2

Volume: 74

Page: 132-136

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 7

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