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author:

Xiao, Jun-Qi (Xiao, Jun-Qi.) [1] | Lin, Kuen-Song (Lin, Kuen-Song.) [2] | Yu, Yan (Yu, Yan.) [3] (Scholars:于岩)

Indexed by:

CPCI-S EI Scopus SCIE

Abstract:

Recently, AgX (X = Cl, Br, I) materials have been demonstrated as novel and efficient visible-light photocatalysts for the decomposition of various organic compounds and dyes. Herein, heterostructured Ag@ AgCl@ AgBr nanotubes were prepared by an anion-exchange reaction between Ag@ AgCl nanotubes and Br- anions, and their photocatalytic activities towards the decomposition of organic pollutants were studied. The as-synthesized photocatalysts were characterized using X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy combined with energy-dispersive X-ray spectroscopy (HR-TEM/EDS), X-ray photoelectron spectroscopy (XPS), and photoluminescence (PL) spectroscopy. The structure characterization studies confirmed that the photocatalysts had nanotubular morphology. Compared to polyhedral Ag@ AgBr nanoparticles, the incorporation of Br-ions into the Ag@ AgCl framework remarkably enhanced the photocatalytic activities. The as-prepared Ag@ AgCl@ AgBr nanotubes can also be reused due to their high stability. Under visible light irradiation,>98.5% of Rhodamine B (RhB) and 90.3% of Red Acid I (RAI) were decomposed within 45 min using the catalyst AB-2 (Cl-/Br- = 1: 1). The catalyst AB-2 displayed higher photocatalytic activity due to its enhanced surface area and photoelectron transfer, attributed to its novel heterostructured configuration.

Keyword:

Ag@AgCl@AgBr composite Dye photodegradation Heterostructured nanotubes Photocatalytic Visible light

Community:

  • [ 1 ] [Xiao, Jun-Qi]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Ecomat Adv Technol, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Yu, Yan]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Ecomat Adv Technol, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Xiao, Jun-Qi]Yuan Ze Univ, Environm Technol Res Ctr, Dept Chem Engn & Mat Sci, Taoyuan 32003, Taiwan
  • [ 4 ] [Lin, Kuen-Song]Yuan Ze Univ, Environm Technol Res Ctr, Dept Chem Engn & Mat Sci, Taoyuan 32003, Taiwan

Reprint 's Address:

  • 于岩

    [Yu, Yan]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Ecomat Adv Technol, Fuzhou 350108, Fujian, Peoples R China;;[Lin, Kuen-Song]Yuan Ze Univ, Environm Technol Res Ctr, Dept Chem Engn & Mat Sci, Taoyuan 32003, Taiwan

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Source :

CATALYSIS TODAY

ISSN: 0920-5861

Year: 2018

Volume: 314

Page: 10-19

4 . 8 8 8

JCR@2018

5 . 2 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 36

SCOPUS Cited Count: 38

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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