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author:

Chen, Yan (Chen, Yan.) [1] | Tan, Li (Tan, Li.) [2] (Scholars:谭理) | Zhang, Hui (Zhang, Hui.) [3] | Zhang, Xue (Zhang, Xue.) [4] | Chen, Qiyuan (Chen, Qiyuan.) [5] | Jiang, Haojie (Jiang, Haojie.) [6] | Ge, Fengjuan (Ge, Fengjuan.) [7] | Wei, Shuai (Wei, Shuai.) [8] | Gao, Xinhua (Gao, Xinhua.) [9] | Wang, Peng (Wang, Peng.) [10]

Indexed by:

EI SCIE

Abstract:

We synthesized a metal-free photocatalyst comprising mesoporous carbon nitride (mpg-C3N4) and carbon nanotubes (CNT), via a facile method involving polymerization of melamine as the precursor in the presence of CNT in refluxing methanol. Under visible light, the CNT/mpg-C3N4 composite resulted in a greater than 8.6 x faster rhodamine B photodecomposition rate compared with bulk graphitic C3N4, and 1.6 x faster compared with pure mpg-C3N4. We attribute the promoted photocatalytic performance of the composite to the synergistic effects of open-ended CNT and mpg-C3N4. The highly interconnected CNT in mpg-C3N4 effectively enhances the transfer of photo-generated electrons, harvests more incident visible light, and provides specific channels for oxygen adsorption and photoreactions. We propose a possible reaction mechanism and report a scavenger experiment that found that superoxide radical (center dot O-2(-)) is mainly responsible for dye photodegradation. The CNT/mpg-C3N4 retained good stability after several cycles. This work supplies a promising method of exploiting a stable, metal-free, efficient, and visible light-driven semiconductor to enhance solar energy use for environmental remediation.

Keyword:

Carbon nanotubes Mesoporous carbon nitride Photocatalysis Visible light

Community:

  • [ 1 ] [Chen, Yan]Xuzhou Inst Technol, Sch Mat & Chem Engn, Xuzhou 221018, Jiangsu, Peoples R China
  • [ 2 ] [Zhang, Hui]Xuzhou Inst Technol, Sch Mat & Chem Engn, Xuzhou 221018, Jiangsu, Peoples R China
  • [ 3 ] [Zhang, Xue]Xuzhou Inst Technol, Sch Mat & Chem Engn, Xuzhou 221018, Jiangsu, Peoples R China
  • [ 4 ] [Chen, Qiyuan]Xuzhou Inst Technol, Sch Mat & Chem Engn, Xuzhou 221018, Jiangsu, Peoples R China
  • [ 5 ] [Jiang, Haojie]Xuzhou Inst Technol, Sch Mat & Chem Engn, Xuzhou 221018, Jiangsu, Peoples R China
  • [ 6 ] [Ge, Fengjuan]Xuzhou Inst Technol, Sch Mat & Chem Engn, Xuzhou 221018, Jiangsu, Peoples R China
  • [ 7 ] [Wei, Shuai]Xuzhou Inst Technol, Sch Mat & Chem Engn, Xuzhou 221018, Jiangsu, Peoples R China
  • [ 8 ] [Wang, Peng]Xuzhou Inst Technol, Sch Mat & Chem Engn, Xuzhou 221018, Jiangsu, Peoples R China
  • [ 9 ] [Tan, Li]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Inst Mol Catalysis & Operando Characterizat, Fuzhou 350108, Peoples R China
  • [ 10 ] [Gao, Xinhua]Ningxia Univ, State Key Lab High Efficiency Utilizat Coal & Gre, Yinchuan 750021, Ningxia, Peoples R China

Reprint 's Address:

  • [Wang, Peng]Xuzhou Inst Technol, Sch Mat & Chem Engn, Xuzhou 221018, Jiangsu, Peoples R China

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Source :

RESEARCH ON CHEMICAL INTERMEDIATES

ISSN: 0922-6168

Year: 2021

Issue: 8

Volume: 47

Page: 3349-3362

3 . 1 3 4

JCR@2021

2 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:117

JCR Journal Grade:3

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 11

SCOPUS Cited Count: 11

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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