Indexed by:
Abstract:
We synthesized a metal-free photocatalyst comprising mesoporous carbon nitride (mpg-C3N4) and carbon nanotubes (CNT), via a facile method involving polymerization of melamine as the precursor in the presence of CNT in refluxing methanol. Under visible light, the CNT/mpg-C3N4 composite resulted in a greater than 8.6 x faster rhodamine B photodecomposition rate compared with bulk graphitic C3N4, and 1.6 x faster compared with pure mpg-C3N4. We attribute the promoted photocatalytic performance of the composite to the synergistic effects of open-ended CNT and mpg-C3N4. The highly interconnected CNT in mpg-C3N4 effectively enhances the transfer of photo-generated electrons, harvests more incident visible light, and provides specific channels for oxygen adsorption and photoreactions. We propose a possible reaction mechanism and report a scavenger experiment that found that superoxide radical (center dot O-2(-)) is mainly responsible for dye photodegradation. The CNT/mpg-C3N4 retained good stability after several cycles. This work supplies a promising method of exploiting a stable, metal-free, efficient, and visible light-driven semiconductor to enhance solar energy use for environmental remediation.
Keyword:
Reprint 's Address:
Email:
Version:
Source :
RESEARCH ON CHEMICAL INTERMEDIATES
ISSN: 0922-6168
Year: 2021
Issue: 8
Volume: 47
Page: 3349-3362
3 . 1 3 4
JCR@2021
2 . 8 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:117
JCR Journal Grade:3
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 11
SCOPUS Cited Count: 11
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
Affiliated Colleges: