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author:

Xiao, Jun-Qi (Xiao, Jun-Qi.) [1] | Mdlovu, Ndumiso Vukile (Mdlovu, Ndumiso Vukile.) [2] | Lin, Kuen-Song (Lin, Kuen-Song.) [3] | Chang, Chi-Jung (Chang, Chi-Jung.) [4] | Chen, Zong-Wei (Chen, Zong-Wei.) [5]

Indexed by:

SCIE

Abstract:

In the current study, heterostructured Ag@AgCl@AgI nanotubes were synthesized via an anion-exchange reaction between Ag@AgCl nanotubes and I- anions. Moreover, their photocatalytic performance towards the decontamination of dye contaminants were examined. These prepared photocatalysts were accordingly characterized using high-resolution scanning electron microscopy (HR-SEM), XRPD, XPS, field-emission transmission electron microscopy (FE-TEM), and photoluminescence (PL) spectroscopy. The structural identification analyses confirmed that the photocatalysts had nanotubular morphology. Compared to polyhedral Ag@AgI nanocomposites, the amalgamation of I- ions into the Ag@AgCl framework extraordinarily improved the photocatalytic performance. The synthesized Ag@AgCl@AgI nanotubes can also be reused due to their high stability. Under visible-light irradiation,> 91.8% of Rhodamine B (RhB) was degraded within 45 min using the catalyst AI-2 (Cl-/I-= 1:1). The radical trap experiments indicated that the photodegradation of RhB was driven by the participation of superoxide radical and the action of holes. Due to the surface plasmon resonance effect, the photocatalyst AI-2 demonstrated higher photocatalytic performance, enhanced surface area and photoelectron transfer, which is also ascribed to its unique heterostructured configuration.

Keyword:

Ag@AgCl@AgI Dye photodegradation Heterostructured nanotube Nanocomposite Photocatalysis Visible-light

Community:

  • [ 1 ] [Xiao, Jun-Qi]Yuan Ze Univ, Dept Chem Engn & Mat Sci, Environm Technol Res Ctr, Taoyuan 32003, Taiwan
  • [ 2 ] [Mdlovu, Ndumiso Vukile]Yuan Ze Univ, Dept Chem Engn & Mat Sci, Environm Technol Res Ctr, Taoyuan 32003, Taiwan
  • [ 3 ] [Lin, Kuen-Song]Yuan Ze Univ, Dept Chem Engn & Mat Sci, Environm Technol Res Ctr, Taoyuan 32003, Taiwan
  • [ 4 ] [Chen, Zong-Wei]Yuan Ze Univ, Dept Chem Engn & Mat Sci, Environm Technol Res Ctr, Taoyuan 32003, Taiwan
  • [ 5 ] [Xiao, Jun-Qi]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Ecomat Adv Technol, Fuzhou 350108, Fujian, Peoples R China
  • [ 6 ] [Chang, Chi-Jung]Feng Chia Univ, Dept Chem Engn, 100 Wenhwa Rd, Taichung 40724, Taiwan

Reprint 's Address:

  • [Lin, Kuen-Song]Yuan Ze Univ, Dept Chem Engn & Mat Sci, Environm Technol Res Ctr, Taoyuan 32003, Taiwan

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Source :

CATALYSIS TODAY

ISSN: 0920-5861

Year: 2020

Volume: 358

Page: 155-163

6 . 7 6 6

JCR@2020

5 . 2 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:160

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 10

SCOPUS Cited Count: 9

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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