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In the current study, heterostructured Ag@AgCl@AgI nanotubes were synthesized via an anion-exchange reaction between Ag@AgCl nanotubes and I- anions. Moreover, their photocatalytic performance towards the decontamination of dye contaminants were examined. These prepared photocatalysts were accordingly characterized using high-resolution scanning electron microscopy (HR-SEM), XRPD, XPS, field-emission transmission electron microscopy (FE-TEM), and photoluminescence (PL) spectroscopy. The structural identification analyses confirmed that the photocatalysts had nanotubular morphology. Compared to polyhedral Ag@AgI nanocomposites, the amalgamation of I- ions into the Ag@AgCl framework extraordinarily improved the photocatalytic performance. The synthesized Ag@AgCl@AgI nanotubes can also be reused due to their high stability. Under visible-light irradiation,> 91.8% of Rhodamine B (RhB) was degraded within 45 min using the catalyst AI-2 (Cl-/I-= 1:1). The radical trap experiments indicated that the photodegradation of RhB was driven by the participation of superoxide radical and the action of holes. Due to the surface plasmon resonance effect, the photocatalyst AI-2 demonstrated higher photocatalytic performance, enhanced surface area and photoelectron transfer, which is also ascribed to its unique heterostructured configuration.
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CATALYSIS TODAY
ISSN: 0920-5861
Year: 2020
Volume: 358
Page: 155-163
6 . 7 6 6
JCR@2020
5 . 2 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:160
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 10
SCOPUS Cited Count: 9
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 3
Affiliated Colleges: