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Abstract ：
Traditional nanofiltration membranes allow high rejection of low molecular weight organic matter, yet suffer from a low flux and a high operation pressure, and they pose an environmental concern because they are made of petroleum-based polymers. Herein, a novel environmentally friendly filter membrane for ultrafast molecular separation has been developed using natural and artificial biomaterials as building units. Cellulose micron fibers, a natural biopolymer, serve as a stable substrate for the growth of hydroxyapatite (HAP) nanowire bunches, which are the main inorganic components of bones and teeth. The vertically aligned HAP nanowire bunches provide abundant nanoscale surfaces and confinement space for the attachment of dopamine and subsequently self-polymerization into polydopamine (PDA) sub-micron particles, which are a melanin-like bioactive polymer. On the one hand, the as-built micro-nano hierarchical configuration enables ultrahigh permeance (>6000 L m(-2) h(-1) bar(-1)) through the filter membrane at a low pressure (62 mbar). On the other hand, molecular dynamics simulations reveal that synergy between multiple molecular interactions of HAP and PDA contributes to the universal separation of different organic pollutants from water (i.e., cationic and anionic dyes and antibiotics) at a high removal rate of > 97 %. Overall, this work ingeniously uses biocompatible biomaterials to build a hierarchical filter membrane, thereby enabling ultrafast and efficient molecular separation.
Keyword ：
Biomaterials Biomaterials Cellulose Cellulose Filter Membranes Filter Membranes Hydroxyapatite Nanowires Hydroxyapatite Nanowires Polydopamine Polydopamine
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| GB/T 7714 | Wu, Linhan , Shi, Dehuan , Lin, Fuwang et al. Ultrafast molecular separation through all-biomaterial membranes with a hierarchical configuration and mechanism study [J]. | SEPARATION AND PURIFICATION TECHNOLOGY , 2025 , 361 . |
| MLA | Wu, Linhan et al. "Ultrafast molecular separation through all-biomaterial membranes with a hierarchical configuration and mechanism study" . | SEPARATION AND PURIFICATION TECHNOLOGY 361 (2025) . |
| APA | Wu, Linhan , Shi, Dehuan , Lin, Fuwang , Chen, Fei-Fei , Yang, Chengkai , Yu, Yan . Ultrafast molecular separation through all-biomaterial membranes with a hierarchical configuration and mechanism study . | SEPARATION AND PURIFICATION TECHNOLOGY , 2025 , 361 . |
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The uncontrolled dendritic growth and severe side reactions significantly constrain zinc-ion batteries' further application. This study presents a novel micellar gel electrolyte, innovatively designed through hydrophobic association. The micellar gel electrolyte harmonizes macroscopic and microscopic properties through a rational hierarchical design. At the macroscopic level, the hydrophilic domains as water-absorbing nets and the hydrophobic domains as pillars are intricately interwoven. On the microscopic scale, the copolymerization resulted in a microphase-separated architecture, with hydrophilic and hydrophobic domains establishing distinct micro-regions within the gel matrix. The hydrophilic domains contribute to the stabilization of the hydrogen bond network through amide groups, while the abundant carbonyl groups optimize the solvation structure and migration pathways of Zn2+. The hydrophobic domains provide a robust supporting framework while simultaneously reducing H2O activity and thereby minimizing parasitic reactions. Thus, the enhanced interfacial stability forms a robust and flexible barrier against dendrite formation. The rational hierarchical gel composition and cross-linked network effectively direct Zn deposition preferentially along the (002) plane, ensuring a uniform and stable interface. The assembled Zn & Vert;MnO2 batteries show 80% capacity retention after 1200 cycles at 1C.
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| GB/T 7714 | Chen, Zheming , Lin, Yushuang , Shi, Dehuan et al. Rational hierarchical micellar gel electrolytes with synergistic hydrophobic-hydrophilic integration for dendrite-free zinc-ion batteries [J]. | JOURNAL OF MATERIALS CHEMISTRY A , 2025 , 13 (9) : 6709-6718 . |
| MLA | Chen, Zheming et al. "Rational hierarchical micellar gel electrolytes with synergistic hydrophobic-hydrophilic integration for dendrite-free zinc-ion batteries" . | JOURNAL OF MATERIALS CHEMISTRY A 13 . 9 (2025) : 6709-6718 . |
| APA | Chen, Zheming , Lin, Yushuang , Shi, Dehuan , Song, Kangwei , Luo, Jing , Qiu, Yanbin et al. Rational hierarchical micellar gel electrolytes with synergistic hydrophobic-hydrophilic integration for dendrite-free zinc-ion batteries . | JOURNAL OF MATERIALS CHEMISTRY A , 2025 , 13 (9) , 6709-6718 . |
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Heterojunction photocatalysts, which consist of two or more semiconductors, have garnered significant attention owing to their extensive benefits, including a broad-spectrum response, efficient carrier separation and migration, as well as robust redox capabilities. Among the myriad of semiconductors, graphitic carbon nitride (g-C3N4) and zinc indium sulfide (ZnIn2S4) have been extensively researched due to their low toxicity, straightforward and scalable synthesis processes, controllable microstructures, and exceptional chemical stability. Recently, there has been a trend towards integrating these two semiconductors to complement each other's strengths. Consequently, a systematic summary and outlook on g-C3N4/ZnIn2S4 heterojunction photocatalysts is both urgent and valuable. This review summarizes the advancements in the g-C3N4/ZnIn2S4 heterojunctions in the last 10 years. We first analyzed the charge-transfer mechanisms in the type-I, type-II, Z-scheme and S-scheme heterojunctions. Then the typical synthesis methods employed for creating g-C3N4/ZnIn2S4 heterojunctions are introduced. Subsequently, we delve into the regulation strategies for g-C3N4/ZnIn2S4 heterojunctions, including morphology optimization, heteroatom doping, defect engineering, and the construction of multinary composites. The design concept and superiorities of these strategies are thoroughly discussed. Following this, we systematically showcase the photocatalytic applications of g-C3N4/ZnIn2S4 heterojunctions, encompassing CO2 reduction, H2 evolution, pollutant degradation, H2O2 production, biomass conversion, photoelectrochemical sensors, and so forth. Last, we propose the challenges that lie ahead in future research endeavors. This comprehensive review is expected to provide an instructive guideline for rational design and applications of g-C3N4/ZnIn2S4 heterojunctions.
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| GB/T 7714 | Lu, Yongjun , Zhuang, Zanyong , Li, Lingyun et al. Advancements and challenges in g-C3N4/ZnIn2S4 heterojunction photocatalysts [J]. | JOURNAL OF MATERIALS CHEMISTRY A , 2025 , 13 (7) : 4718-4745 . |
| MLA | Lu, Yongjun et al. "Advancements and challenges in g-C3N4/ZnIn2S4 heterojunction photocatalysts" . | JOURNAL OF MATERIALS CHEMISTRY A 13 . 7 (2025) : 4718-4745 . |
| APA | Lu, Yongjun , Zhuang, Zanyong , Li, Lingyun , Chen, Fei-Fei , Wei, Peishu , Yu, Yan . Advancements and challenges in g-C3N4/ZnIn2S4 heterojunction photocatalysts . | JOURNAL OF MATERIALS CHEMISTRY A , 2025 , 13 (7) , 4718-4745 . |
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An ideal solid-state electrolyte needs to combine the properties of high ionic conductivity, wide electrochemical stability window, high electrode-electrolyte chemical compatibility, and low cost. Composite solid-state electrolyte is one of the feasible ways to solve this problem. In this work, a composite solid-state electrolyte Li2ZnSiO4 (LZSO)/ LiAlCl4 is reported. The low melting-point LiAlCl4 is introduced to solve the interfacial impedance problem of LZSO solid-state electrolyte due to the hardness of the particles. The structure and electrochemical properties of the two compositions were also characterized, and the effects of different composite ratios on the ionic conductivity of the composite solid-state electrolyte and the low-temperature healing surface structure on the performance enhancement were investigated. The optimal ratio LZSO/LiAlCl4 (7:3) exhibits good interfacial contactness and an ionic conductivity of 1.65 x 10(-4) S cm(-1) at 60 degrees C as well as a low activation energy of 0.31 eV. The assembled lithium symmetric batteries were stably cycled up to 750 h. Compared with the single component of LZSO, which cannot satisfy the full-cell assembly, Li/LFP batteries assembled with composite solid-state electrolytes exhibit good cycling performance.
Keyword ：
Interfacial healing Interfacial healing Li2ZnSiO4 Li2ZnSiO4 LiAlCl4 LiAlCl4 Solid-state lithium metal batteries Solid-state lithium metal batteries
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| GB/T 7714 | Xu, Chenyuan , Chao, Yu , Yang, Sisheng et al. A halide-oxide composite solid-state electrolyte for enhancing ionic conductivity by promoting interfacial healing through low-temperature heat treatment [J]. | JOURNAL OF SOLID STATE ELECTROCHEMISTRY , 2025 . |
| MLA | Xu, Chenyuan et al. "A halide-oxide composite solid-state electrolyte for enhancing ionic conductivity by promoting interfacial healing through low-temperature heat treatment" . | JOURNAL OF SOLID STATE ELECTROCHEMISTRY (2025) . |
| APA | Xu, Chenyuan , Chao, Yu , Yang, Sisheng , Li, Borong , Yu, Yan , Xu, Xiaoming et al. A halide-oxide composite solid-state electrolyte for enhancing ionic conductivity by promoting interfacial healing through low-temperature heat treatment . | JOURNAL OF SOLID STATE ELECTROCHEMISTRY , 2025 . |
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Low-dimensional materials with charge density waves (CDW) are attractive for their potential to exhibit superconductivity and nontrivial topological electronic features. Here we report the two-dimensional (2D) chalcogenide, BaSbTe2S which acts as a new platform hosting these phenomena. The crystal structure of BaSbTe2S is composed of alternating atomically thin Te square-net layers and double rock-salt type [(SbTeS)2]2- slabs separated with Ba2+ atoms. Due to the electronic instability of the Te square net, an incommensurately modulated structure is triggered and confirmed by both single-crystal X-ray diffraction, electron diffraction, and the presence of an energy bandgap in this compound. Our first-principles electronic structure analysis and investigation of structural dynamical instability suggest that the Te network plays a dominant role in its origin. The incommensurate structure is refined with a modulation vector of q = 0.351(1)b* using an orthorhombic cell of a = 4.4696(5) & Aring;, b = 4.4680(5) & Aring;, and c = 15.999(2) & Aring; under superspace group Pmm2(0 beta 0)000 at 293 K. The modulation vector q varies as a function of both occupancy of Te in the square net and temperature, indicating the CDW order can be modulated by local distortions. The CDW can be suppressed by pressure, leading to the emergence of superconductivity with a T c up to 7.5 K at 13.6 GPa, suggesting a competition between the CDW order and superconductivity. Furthermore, electrical transport under the magnetic field reveals the existence of compensated high mobility electron- and hole-bands near the Fermi surface (mu similar to 600-3500 cm2V-1s-1), suggesting Dirac-like band dispersion.
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| GB/T 7714 | Luo, Zhong-Zhen , Zhao, Hengdi , Cai, Weizhao et al. Charge Density Wave and Superconductivity in BaSbTe2S Heterolayer Crystal with 2D Te Square Nets [J]. | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY , 2025 , 147 (8) : 6753-6762 . |
| MLA | Luo, Zhong-Zhen et al. "Charge Density Wave and Superconductivity in BaSbTe2S Heterolayer Crystal with 2D Te Square Nets" . | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 147 . 8 (2025) : 6753-6762 . |
| APA | Luo, Zhong-Zhen , Zhao, Hengdi , Cai, Weizhao , Shahabfar, Shima , Li, Juncen , Cai, Songting et al. Charge Density Wave and Superconductivity in BaSbTe2S Heterolayer Crystal with 2D Te Square Nets . | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY , 2025 , 147 (8) , 6753-6762 . |
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In the quest to align with industrial benchmarks, a noteworthy gap remains in the field of electrochemical nitrogen fixation, particularly in achieving high Faradaic efficiency (FE) and yield. The electrocatalytic nitrogen fixation process faces considerable hurdles due to the difficulty in cleaving the highly stable NN triple bond. Additionally, the electrochemical pathway for nitrogen fixation is often compromised by the concurrent hydrogen evolution reaction (HER), which competes aggressively for electrons and active sites on the catalyst surface, thereby reducing the FE of nitrogen reduction reaction (NRR). To surmount these challenges, this study introduces an innovative bimetallic catalyst, CuGa2, synthesized through p-d orbital hybridization to selectively facilitate N2 electroreduction. This catalyst has demonstrated a remarkable NH3 yield of 9.82 mu g h-1 cm-2 and an associated FE of 38.25%. Our findings elucidate that the distinctive p-d hybridization interaction between Ga and Cu enhances NH3 selectivity by reducing the reaction energy barrier for hydrogenation and suppressing hydrogen evolution. This insight highlights the significance of p-d orbital hybridization in optimizing the electrocatalytic performance of CuGa2 for nitrogen fixation.
Keyword ：
Bimetallic catalyst Bimetallic catalyst CuGa 2 alloy CuGa 2 alloy Electrochemical nitrogen fixation Electrochemical nitrogen fixation Liquid metals Liquid metals p -d orbital hybridization p -d orbital hybridization
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| GB/T 7714 | Chen, Bin , Zheng, Chaoyang , Shi, Dehuan et al. p-d orbital hybridization induced by CuGa2 promotes selective N2 electroreduction [J]. | CHINESE JOURNAL OF STRUCTURAL CHEMISTRY , 2025 , 44 (1) . |
| MLA | Chen, Bin et al. "p-d orbital hybridization induced by CuGa2 promotes selective N2 electroreduction" . | CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 44 . 1 (2025) . |
| APA | Chen, Bin , Zheng, Chaoyang , Shi, Dehuan , Huang, Yi , Deng, Renxia , Wei, Yang et al. p-d orbital hybridization induced by CuGa2 promotes selective N2 electroreduction . | CHINESE JOURNAL OF STRUCTURAL CHEMISTRY , 2025 , 44 (1) . |
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Birefringent crystals play an irreplaceable role in optical systems by adjusting the polarization state of light in optical devices. This work successfully synthesized a new thiophosphate phase of B-Pb3 P2 S8 through the high-temperature solid-state spontaneous crystallization method. Different from the cubic a-Pb3 P2 S8 , the B-Pb3 P2 S8 crystallizes in the orthorhombic Pbcn space group. Notably, B-Pb3 P2 S8 shows a large band gap of 2.37 eV in lead-based chalcogenides, wide infrared transparent window (2.5-15 mu m), and excellent thermal stability. Importantly, the experimental birefringence shows the largest value of 0.26@550 nm in chalcogenides, even larger than the commercialized oxide materials. The Barder charge analysis result indicates that the exceptional birefringence effect is mainly from the Pb2 + and S2- in the [PbSn ] polyhedrons. Meanwhile, the parallelly arranged polyhedral layers could improve the structural anisotropic. Therefore, this work supports a new method for designing chalcogenides with exceptional birefringence effect in the infrared region. (c) 2024 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.
Keyword ：
Birefringent crystals Birefringent crystals Chalcogenides Chalcogenides Optical properties Optical properties Structural ansotropic Structural ansotropic
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| GB/T 7714 | Guo, Weiping , Zhu, Ying , Cui, Hong-Hua et al. B-Pb 3 P 2 S 8: A new optical crystal with exceptional birefringence effect [J]. | CHINESE CHEMICAL LETTERS , 2025 , 36 (2) . |
| MLA | Guo, Weiping et al. "B-Pb 3 P 2 S 8: A new optical crystal with exceptional birefringence effect" . | CHINESE CHEMICAL LETTERS 36 . 2 (2025) . |
| APA | Guo, Weiping , Zhu, Ying , Cui, Hong-Hua , Li, Lingyun , Yu, Yan , Luo, Zhong-Zhen et al. B-Pb 3 P 2 S 8: A new optical crystal with exceptional birefringence effect . | CHINESE CHEMICAL LETTERS , 2025 , 36 (2) . |
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Herein, we report a hydrogen-bonded supramolecular hybrid composed of a cobaloxime complex and a covalent organic framework (COF) that achieves photocatalytic overall water splitting. The designed COF features ternary units and dual linkages, which induce asymmetric linkers. Upon photoexcitation, this asymmetry facilitates directed electron transfer and spatially separated redox sites, resulting in a long-lived charge-separated state. Consequently, the COF, hydrogen-bonded with cobaloxime as a hydrogen (H2) production cocatalyst, enables visible-light photocatalytic overall water splitting, simultaneously producing H2 and hydrogen peroxide (H2O2), outperforming the COFs with symmetric linker structures. This strategy of asymmetric structural design offers new insights for the design of photocatalysts with suppressed charge recombination for photocatalysis.
Keyword ：
Asymmetric structure Asymmetric structure Covalent organic framework Covalent organic framework Overall water splitting Overall water splitting Photocatalysis Photocatalysis Single site Single site
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| GB/T 7714 | Yu, Mingfei , Huang, Junhan , Niu, Qing et al. Asymmetric Structural Design in Cobaloxime-Integrated Covalent Organic Frameworks to Facilitate Photocatalytic Overall Water Splitting [J]. | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2025 . |
| MLA | Yu, Mingfei et al. "Asymmetric Structural Design in Cobaloxime-Integrated Covalent Organic Frameworks to Facilitate Photocatalytic Overall Water Splitting" . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2025) . |
| APA | Yu, Mingfei , Huang, Junhan , Niu, Qing , Li, Liuyi , Yu, Yan , Bi, Jinhong . Asymmetric Structural Design in Cobaloxime-Integrated Covalent Organic Frameworks to Facilitate Photocatalytic Overall Water Splitting . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2025 . |
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Herein, a versatile amorphous-to-crystalline transformation (ACT) strategy is described, to furnish various metals (Cu, Co, Ni, Cs, and Y) based atomically dispersed catalysts (ADCs) on thin holey 2D Al2O3. This approach, which involves adjusting reactant stoichiometry, enables the continuous modulation of particle size of ADCs at an atomical level, giving the ultrafine products as single atom, cluster, or nanoparticle catalysts. This synthesis method allows a straightforward analysis and comparison of the reactivity of the ADCs catalysts based on the dispersion of the active metal. In the case of Cu, the cluster catalyst 0.2-Cu/Al2O3 outperforms the single atom catalyst 0.1-Cu/Al2O3 and the nanoparticle catalyst 0.3-Cu/Al2O3 in the oxidation of refractory organic molecules, thanks to its superior electron transport and surface adsorption properties. These findings are well supported by the Density functional theory (DFT) calculations. Additionally, this method facilitates the preparation of atomic clusters with a very small size of 0.5-1 nm, composed of just a few atoms, as exemplified by Ni-based ADCs. The developed synthesis enriches the library of ADCs and demonstrates the potential of amorphous-to-crystalline transformation in creating advanced ultrasmall functional materials.
Keyword ：
amorphous-to-crystalline transformation amorphous-to-crystalline transformation atomically dispersed catalysts atomically dispersed catalysts cluster, precise size tailoring cluster, precise size tailoring single atom single atom
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| GB/T 7714 | Wang, Yaping , Zhang, Tingshi , Huang, Xinlian et al. Amorphous-to-Crystalline Transformation for Tunable Synthesis of Single Atom, Cluster, and Nanoparticle Catalysts: Dispersion of Metal Elements (Cu, Co, Ni, Y, Cs) on Holey 2D Ultra-Thin Al2O3 Nanosheets [J]. | SMALL METHODS , 2025 . |
| MLA | Wang, Yaping et al. "Amorphous-to-Crystalline Transformation for Tunable Synthesis of Single Atom, Cluster, and Nanoparticle Catalysts: Dispersion of Metal Elements (Cu, Co, Ni, Y, Cs) on Holey 2D Ultra-Thin Al2O3 Nanosheets" . | SMALL METHODS (2025) . |
| APA | Wang, Yaping , Zhang, Tingshi , Huang, Xinlian , Zeng, Yurong , Wei, Siyuan , Zhuang, Zanyong et al. Amorphous-to-Crystalline Transformation for Tunable Synthesis of Single Atom, Cluster, and Nanoparticle Catalysts: Dispersion of Metal Elements (Cu, Co, Ni, Y, Cs) on Holey 2D Ultra-Thin Al2O3 Nanosheets . | SMALL METHODS , 2025 . |
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Modulating interfacial electrochemistry represents a prevalent approach for mitigating lithium dendrite growth and enhancing battery performance. Nevertheless, while most additives exhibit inhibitory characteristics, the accelerating effects on interfacial electrochemistry have garnered limited attention. In this work, perfluoromorpholine (PFM) with facilitated kinetics is utilized to preferentially adsorb on the lithium metal interface. The PFM molecules disrupt the solvation structure of Li+ and enhance the migration of Li+. Combined with the benzotrifluoride, a synergistic acceleration-inhibition system is formed. The ab initio molecular dynamics (AIMD) and density functional theory (DFT) calculation of the loose outer solvation clusters and the key adsorption–deposition step supports the fast diffusion and stable interface electrochemistry with an accelerated filling mode with C─F and C─H groups. The approach induces the uniform lithium deposition. Excellent cycling performance is achieved in Li||Li symmetric cells, and even after 200 cycles in Li||NCM811 full cells, 80% of the capacity is retained. This work elucidates the accelerated electrochemical processes at the interface and expands the design strategies of acceleration fluorinated additives for lithium metal batteries. © 2024 Wiley-VCH GmbH.
Keyword ：
acceleration acceleration AIMD AIMD interfacial adsorption interfacial adsorption lithium metal batteries lithium metal batteries outer and inner solvation cluster outer and inner solvation cluster
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| GB/T 7714 | Zheng, X. , Qiu, Y. , Luo, J. et al. Perfluorinated Amines: Accelerating Lithium Electrodeposition by Tailoring Interfacial Structure and Modulated Solvation for High-Performance Batteries [J]. | Small , 2024 , 20 (44) . |
| MLA | Zheng, X. et al. "Perfluorinated Amines: Accelerating Lithium Electrodeposition by Tailoring Interfacial Structure and Modulated Solvation for High-Performance Batteries" . | Small 20 . 44 (2024) . |
| APA | Zheng, X. , Qiu, Y. , Luo, J. , Yang, S. , Yu, Y. , Liu, Z. et al. Perfluorinated Amines: Accelerating Lithium Electrodeposition by Tailoring Interfacial Structure and Modulated Solvation for High-Performance Batteries . | Small , 2024 , 20 (44) . |
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