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author:

Zhang, Weiying (Zhang, Weiying.) [1] (Scholars:张卫英) | Yun, Mengying (Yun, Mengying.) [2] | Yu, Zhenlin (Yu, Zhenlin.) [3] | Chen, Dan (Chen, Dan.) [4] | Li, Xiao (Li, Xiao.) [5] (Scholars:李晓)

Indexed by:

EI Scopus SCIE

Abstract:

A novel Cu(II) ion-imprinted complex adsorbent [Cu(II)-IIP] from alginate and chitosan was prepared by a three-step process of beading-combining-crosslinking with Cu2+ as the template ion. The Cu(II)-IIP showed higher capacity and selectivity for Cu(II) than the non-imprinted polymer. The theoretical maximum adsorption capacity of Cu(II)-IIP reached 83.33mg/g, and the separation factor () for Cu(II) versus Zn(II) was 2.28. The adsorption of Cu2+ onto the Cu(II)-IIP was perfectly described by the Langmuir isotherm model. The adsorption kinetics agreed with the pseudo-first-order model in the first 8h and more fitted pseudo-second-order model after then. Weber-Morris model confirmed that the adsorption rate would be controlled dominantly by the intraparticle diffusion and the inner surface binding. Moreover, the Cu(II)-IIP complex adsorbent exhibited good regeneration, and the adsorption capacity was stable within the first three adsorption-desorption cycles without significant reduction.

Keyword:

Adsorption Alginate Chitosan Complex Cu(II) ion Ion imprinting

Community:

  • [ 1 ] [Zhang, Weiying]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Yun, Mengying]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Yu, Zhenlin]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Chen, Dan]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 5 ] [Li, Xiao]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • 李晓

    [Li, Xiao]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Fujian, Peoples R China

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Source :

POLYMER BULLETIN

ISSN: 0170-0839

Year: 2019

Issue: 4

Volume: 76

Page: 1861-1876

2 . 0 1 4

JCR@2019

3 . 1 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:184

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 27

SCOPUS Cited Count: 35

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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