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Abstract:
A novel Cu(II) ion-imprinted complex adsorbent [Cu(II)-IIP] from alginate and chitosan was prepared by a three-step process of beading-combining-crosslinking with Cu2+ as the template ion. The Cu(II)-IIP showed higher capacity and selectivity for Cu(II) than the non-imprinted polymer. The theoretical maximum adsorption capacity of Cu(II)-IIP reached 83.33mg/g, and the separation factor () for Cu(II) versus Zn(II) was 2.28. The adsorption of Cu2+ onto the Cu(II)-IIP was perfectly described by the Langmuir isotherm model. The adsorption kinetics agreed with the pseudo-first-order model in the first 8h and more fitted pseudo-second-order model after then. Weber-Morris model confirmed that the adsorption rate would be controlled dominantly by the intraparticle diffusion and the inner surface binding. Moreover, the Cu(II)-IIP complex adsorbent exhibited good regeneration, and the adsorption capacity was stable within the first three adsorption-desorption cycles without significant reduction.
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POLYMER BULLETIN
ISSN: 0170-0839
Year: 2019
Issue: 4
Volume: 76
Page: 1861-1876
2 . 0 1 4
JCR@2019
3 . 1 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:184
JCR Journal Grade:2
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 27
SCOPUS Cited Count: 35
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 4
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