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author:

Chen, Jianfu (Chen, Jianfu.) [1] | Zhang, Weiying (Zhang, Weiying.) [2] (Scholars:张卫英) | Li, Xiao (Li, Xiao.) [3] (Scholars:李晓)

Indexed by:

EI Scopus SCIE

Abstract:

A novel adsorbent, biodegradable Konjac glucomannan-poly(acrylic acid) (KGMP) hydrogel, is prepared by Konjac glucomannan grafting with acrylic acid. The adsorption properties of the KGMP for Cu(II) ion removal from aqueous solutions are investigated. The experiments are performed under various impact factors such as initial Cu(II) ion concentration, pH, contact time, temperature and salt ionic strength. The Langmuir and Freundlich isotherm are employed to discuss the adsorption behavior. The result shows the equilibrium data obtained at different temperatures are represented perfectly by Langmuir isotherm model compared to the Freundlich isotherm models. The monolayer saturation adsorption capacities of KGMP for Cu(II) ion is found to be 27.1739, 30.2115, 34.1297 and 41.6667 mg g(-1) at 298, 303, 308 and 313 K, respectively. Thermodynamic parameters such as Delta G, Delta H and Delta S are calculated. The kinetics studies show that adsorption process follows the pseudo-second-order model and the adsorption process is mainly controlled by both surface reactivity and intra-particle diffusion. FT-IR analysis shows that a large number of carbonyl, ester, and hydroxyl groups are included in the external surface of the KGMP, SEM indicates that the rough, irregular and pores of different size and shapes on surfaces of the KGMP are observed before adsorption. The present study indicates that the KGMP is an effective adsorbent for the removal of Cu(II) ion from aqueous solutions.

Keyword:

Adsorption Cu(II) ion Hydrogel Konjac glucomannan

Community:

  • [ 1 ] [Chen, Jianfu]Fuzhou Univ, Sch Chem Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Zhang, Weiying]Fuzhou Univ, Sch Chem Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Li, Xiao]Fuzhou Univ, Sch Chem Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Chen, Jianfu]Zhangzhou Inst Technol, Dept Food & Biol Engn, Zhangzhou 363000, Fujian, Peoples R China

Reprint 's Address:

  • 张卫英

    [Zhang, Weiying]Fuzhou Univ, Sch Chem Engn, Fuzhou 350108, Fujian, Peoples R China

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Source :

POLYMER BULLETIN

ISSN: 0170-0839

Year: 2016

Issue: 7

Volume: 73

Page: 1965-1984

1 . 4 3

JCR@2016

3 . 1 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:235

JCR Journal Grade:3

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 32

SCOPUS Cited Count: 36

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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