Two　unique　heterometallic　cluster　organic　frameworks,　[(Cd4Mn4Mn6II)-Mn-III(Tri)(4)(CH3COO)(14)(mu(4)-O)(2)(mu(3)-O)(2)(H2O)(2)]　Cd(H2O)(2)9　H2O　(1)　and　Cu[Cd5Cu6(Tri)(4)(CH3COO)(9)(H2O)(4)](2)(CH3COO)(3)24　H2O　(2)　(H(3)Tri=2-(hydroxymethyl)-2-(pyridine-4-yl)-1,3-propanediol),　have　been　successfully　prepared　by　employing　a　bifunctional　tripodal　alcohol　ligand　as　a　structure-directing　agent.　Crystal　structure　analyses　reveal　that　1　represents　a　rare　example　of　frameworks　constructed　from　Cd-Mn　heterometallic　chains,　and　2　is　the　first　heterometallic　MOF　based　on　highest-nuclear　Cd-Cu　heterometallic　cluster　building　blocks.　Furthermore,　the　magnetic　properties　and　gas　adsorption　abilities　of　1　and　2　were　systematically　studied.